tallium trihydride | 692247-53-3

• 英文名称: tallium trihydride
• CAS: 692247-53-3
• 化学式: H₃Tl
• 分子量: 210.383
• InChiKey: NWUWMQRSDSSETA-XCIZNGPVSA-N

反应信息

• 作为产物：
  描述：

  thallium 、 氘 以 gaseous matrix 为溶剂， 生成 、 thallium monodeuteride 、 tallium dihydride 、 tallium trihydride
  参考文献：
  名称：

  氢化氢在固态氢和固态茚满中的红外光谱。

  摘要：

  One little indium: Reactions of laser‐ablated indium atoms with pure hydrogen give sharp IR absorptions corresponding to InH intermediate species. Irradiation at 193 nm maximizes further reaction to give the indane monomer InH3. Annealing provides evidence for In2H6 and ultimately the sharp absorption bands are replaced with a broad IR band centered at 1460 cm−1 assigned to solid indane (InH3)n [see Equation].${\vcenter{\openup.5em\halign{$#$\cr {\rm InH}_{3}\rightarrow {1\over 2}{\rm In}_{2}{\rm H}_{6}\rightarrow {1\over n}({\rm InH}_{3})_{n}\hfill\cr}}}$

  DOI：

  10.1002/anie.200353216