[Re2(μ-H)(μ:η3-C12H9N2)(CO)7] | 751186-04-6

• 英文名称: [Re2(μ-H)(μ:η3-C12H9N2)(CO)7]
• CAS: 751186-04-6
• 化学式: C₁₉H₁₀N₂O₇Re₂
• 分子量: 750.712
• InChiKey: FCJYQVBYOOWNLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Re2(μ-H)(μ:η3-C12H9N2)(CO)7] 以 环己烷 为溶剂， 以62%的产率得到[Re2(μ-H)(μ:η4-C12H9N2)(CO)6]
  参考文献：
  名称：

  Synthesis and molecular structure of [Re2(μ:η6-C24H18N4)(CO)6] containing the rtct-tetrakis(2-pyridyl)cyclobutandiyl ligand, derived from the reaction of [Re2(CO)8(MeCN)2] and 1,2-bis(2-pyridyl)ethene

  摘要：

  The reaction of the labile compound [Re-2(CO)(8)(CH3CN)(2)] with trans-1,2-bis(2-pyridyl)ethene (C12H10N2) at room temperature in tetrahydrofuran affords the compounds [Re-2(mu:eta(3)-C12H10N2)(CO)(8)] (1) and the oxidative addition product [Re-2(mu-H)(mu:eta(3)- C12H9N2)(CO)(7)] (2). When the reaction is carried out at temperatures of refluxing tetrahydrofuran, besides compounds 1 and 2, the oxidative addition product [Re-2(mu-H)(mu:eta(4)-C12H9N2)(CO)(6)] (3), the insertion product [Re-2(mu:eta(4)-C12H10N2)(CO)(8)] (4) and [Re-2(mu:eta(6)-C14H18N4)(CO)(6)] (5) are obtained. Compound 5 contains the organic ligand rtct-tetrakis(2-pyridyl)cyclobutandiyl which is derived from a [2 + 2] cycloaddition of 1,2-bis(2-pyridyl)ethene mediated by its coordination to the bimetallic framework. The molecular structures of 1, 2, 4 and 5 were confirmed by X-ray crystallographic studies. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.05.005
• 作为产物：
  描述：

  [Re2(μ-H)(μ:η4-C12H9N2)(CO)6] 、 一氧化碳 以 氘代丙酮 为溶剂， 生成 [Re2(μ-H)(μ:η3-C12H9N2)(CO)7]
  参考文献：
  名称：

  Synthesis and molecular structure of [Re2(μ:η6-C24H18N4)(CO)6] containing the rtct-tetrakis(2-pyridyl)cyclobutandiyl ligand, derived from the reaction of [Re2(CO)8(MeCN)2] and 1,2-bis(2-pyridyl)ethene

  摘要：

  The reaction of the labile compound [Re-2(CO)(8)(CH3CN)(2)] with trans-1,2-bis(2-pyridyl)ethene (C12H10N2) at room temperature in tetrahydrofuran affords the compounds [Re-2(mu:eta(3)-C12H10N2)(CO)(8)] (1) and the oxidative addition product [Re-2(mu-H)(mu:eta(3)- C12H9N2)(CO)(7)] (2). When the reaction is carried out at temperatures of refluxing tetrahydrofuran, besides compounds 1 and 2, the oxidative addition product [Re-2(mu-H)(mu:eta(4)-C12H9N2)(CO)(6)] (3), the insertion product [Re-2(mu:eta(4)-C12H10N2)(CO)(8)] (4) and [Re-2(mu:eta(6)-C14H18N4)(CO)(6)] (5) are obtained. Compound 5 contains the organic ligand rtct-tetrakis(2-pyridyl)cyclobutandiyl which is derived from a [2 + 2] cycloaddition of 1,2-bis(2-pyridyl)ethene mediated by its coordination to the bimetallic framework. The molecular structures of 1, 2, 4 and 5 were confirmed by X-ray crystallographic studies. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.05.005