| 1248334-81-7

• CAS: 1248334-81-7
• 化学式: C₂₃H₃₉MnO₂S
• 分子量: 434.565
• InChiKey: DYQXEHATMQLDQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三羰基(η-环戊二烯基)合锰 、 1-十六烷硫醇 以 环己烷 为溶剂， 生成
  参考文献：
  名称：

  CpMn(CO)₃-Catalyzed Photoconversion of Thiols into Disulfides and Dihydrogen

  摘要：

  The UV photolysis of CpMn(CO)(3) with thiols at room temperature effected the following catalytic transformation: 2 RSH --> H-2. This reaction is a cleaner and greener way toward making disulfides, as it produces dihydrogen as the only side-product. The manganese system exhibits high chemoselectivity as the transformation proceeds efficiently even in the presence of numerous functional groups. A manganese dicarbonyl complex, CpMn(CO)(2)RSH, and cyclopentadiene have also been detected using FTIR and NMR spectroscopic techniques, respectively. Based on our experimental data, a mechanism has been proposed to account for the catalysis.

  DOI：

  10.1021/om1005947