[Pt(Me)(η(2)-CH2=CH2)(1,10-phenanthroline)]BF4 | 186534-92-9

• 英文名称: [Pt(Me)(η(2)-CH2=CH2)(1,10-phenanthroline)]BF4
• 英文别名: [Pt(Me)(1,10-phenanthroline)(ethylene)](BF4)
• CAS: 186534-92-9
• 化学式: BF₄*C₁₅H₁₅N₂Pt
• 分子量: 505.182
• InChiKey: FIKGXWJPPSSOQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pt(Me)(η(2)-CH2=CH2)(1,10-phenanthroline)]BF4 、 potassium dimethyl malonate 以 四氢呋喃 为溶剂， 生成 Pt(Me)(CH(CO2Me)2)(1,10-phenanthroline)
  参考文献：
  名称：

  New square-planar cationic Pt(II) complexes containing a methyl and an olefin in cis position

  摘要：

  An effective method for the synthesis of square-planar cationic Pt(II) complexes containing a methyl and an olefin in cis position is described. The addition of Me(3)OBF(4) to [Pt(phen)(eta(2)-E-MeO(2)CCH = CHCO2 Me)] affords the cationic olefin complex [PtMe(phen)(eta(2)-E-MeO(2)CCH=CHCO(2)Me)](+) (BF4-). Dimethylfumarate is easily displaced by electron-rich olefins RCH = CH2 (R = H, Ph, Me) and the products [PtMe(phen)(eta(2)-RCH=CH2)](+)(BF4-) can be isolated in good yield.

  DOI：

  10.1016/s0022-328x(96)06514-x
• 作为产物：
  描述：

  乙烯 、 [Pt(Me)(η(2)-E-MeO2CCH=CHCO2Me)(1,10-phenanthroline)]BF4 以 硝基甲烷 为溶剂， 生成 [Pt(Me)(η(2)-CH2=CH2)(1,10-phenanthroline)]BF4
  参考文献：
  名称：

  New square-planar cationic Pt(II) complexes containing a methyl and an olefin in cis position

  摘要：

  An effective method for the synthesis of square-planar cationic Pt(II) complexes containing a methyl and an olefin in cis position is described. The addition of Me(3)OBF(4) to [Pt(phen)(eta(2)-E-MeO(2)CCH = CHCO2 Me)] affords the cationic olefin complex [PtMe(phen)(eta(2)-E-MeO(2)CCH=CHCO(2)Me)](+) (BF4-). Dimethylfumarate is easily displaced by electron-rich olefins RCH = CH2 (R = H, Ph, Me) and the products [PtMe(phen)(eta(2)-RCH=CH2)](+)(BF4-) can be isolated in good yield.

  DOI：

  10.1016/s0022-328x(96)06514-x