(η(4)-MeC5H5)Fe(CO)2(μ-η(1):η(1)-dppm)W(CO)5 | 185154-17-0

• 英文名称: (η(4)-MeC5H5)Fe(CO)2(μ-η(1):η(1)-dppm)W(CO)5
• CAS: 185154-17-0
• 化学式: C₃₈H₃₀FeO₇P₂W
• 分子量: 900.297
• InChiKey: OVZIQBVTYFRTTR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tungsten pentacarbonyl tetrahydrofuran 、 (η(4)-MeC5H5)Fe(CO)2(η(1)-Ph2PCH2PPh2) 以 四氢呋喃 为溶剂， 以88%的产率得到(η(4)-MeC5H5)Fe(CO)2(μ-η(1):η(1)-dppm)W(CO)5
  参考文献：
  名称：

  Neighboring Metal-Induced Oxidative Addition in Conjunction with a Hydride Trap:  Formation of [(η⁵-MeC₅H₄)Fe(CO)(μ-η¹:η¹-PPh₂CH₂PPh₂)(μ-H)M(CO)₄] (M = W, Mo)

  摘要：

  The reaction of (eta(4)-MeC(5)H(5))Fe(CO)2(eta(1)-dppm), 1, with M(CO)(3)L(3) produced (eta 5-MeC(5)H(4))Fe(CO)(mu-eta(1);eta(1)-dppm)(mu-H)M(CO)(4), 3 (L(3) = (C2H5CN)(3), (THF)(3), C7H8; M = W, Mo). The novel hydride-bridged Fe(II)-M(0) compound was likely formed via the following steps: coordination of the monodentate dppm to M and then CO migration from Fe to M with a sequential or concerted oxidative addition of the endo-C-H bond of the eta(4)-MeC(5)H(5) ligand to give the (eta 5-MeC(5)H(4))FeH complex, followed by a trapping of the Fe-H bond by M forming a six-membered heterocyclic ring in 3.

  DOI：

  10.1021/om9608061