| 186147-99-9

• CAS: 186147-99-9
• 化学式: AuF₁₂Sb₂
• 分子量: 668.447
• InChiKey: YEBDPPUSWKWIPC-UHFFFAOYSA-B

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三氟金 、 氢氟酸 、 五氟化锑 以 neat (no solvent) 为溶剂， 生成 、
  参考文献：
  名称：

  The Reduction of AuF3 in Super Acidic Solution

  摘要：

  AuF3 is reduced in superacidic HF/SbF5 solutions giving three products. 1. Orange [Au3F8 . 2SbF(5)]. It has a layered structure built up by square planar (AuF4)-F-II and (AuF4)-F-III units: Crystal structure: space group P2(1)/c. a = 9.049(2), b = 8.424(1), c = 9.645(1) Angstrom, beta = 115.08(1)degrees. 2. Black [Au3F7 . 3SbF(5)] has a ribbon structure, similarly built up by square planar (AuF4)-F-II and Au(III)F4 units: Crystal structure: space group Pc, a = 9.991(1), b = 10.728(1), c 15.222(1)Angstrom beta = 95.304(2)degrees. 3. Yellow green [(Au(HF)(2)] (SbF6)(2) . 2HF with square planar (AuF4)-F-II units that are formed by two fluorine atoms of the anions and two HF molecules as complex ligands. Crystal structure: Space group P(1) over bar, a = 5.4820) b = 5.8480). c = 9.309(2) Angstrom, alpha = 89.522(4), beta = 85.635(4), gamma = 87.509(4)degrees.

  DOI：

  10.1002/1521-3749(200205)628:4<765::aid-zaac765>3.0.co;2-e