Heterobimetallic complexes of copper with molybdenum and tungsten, X-ray crystal and molecular structure of two isomeric forms of [CuW(CO)<sub>3</sub>(PPh<sub>3</sub>)<sub>2</sub>(η-C<sub>5</sub>H<sub>5</sub>)]
作者:Laurence Carlton、W. Edward Lindsell、Kevin J. McCullough、Peter N. Preston
DOI:10.1039/c39830000216
日期:——
The new, binuclear complexes [CuM(CO)3(PPh3)2(η-C5H5)](M = Mo, W) are described and the structures of two isomeric, crystalline forms of [CuW(CO)3(PPh3)2(η-C5H5)], one possessing distinctly bridging CO groups, are established by X-ray analysis.
描述了新的双核络合物[CuM(CO)3(PPh 3)2(η- C 5 H 5)](M = Mo,W),并显示了[CuW(CO)3的两种异构晶体形式的结构。通过X射线分析建立具有明显桥连的CO基团的(PPh 3)2(η- C 5 H 5)] 。