[Cu2(H2O)2Cl4(3,5-diphenyl-4-amino-1,2,4-triazole)2] | 920274-62-0

• 英文名称: [Cu2(H2O)2Cl4(3,5-diphenyl-4-amino-1,2,4-triazole)2]
• CAS: 920274-62-0
• 化学式: C₂₈H₂₈Cl₄Cu₂N₈O₂
• 分子量: 777.487
• InChiKey: JNKTZISZGBCQIV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu2(H2O)2Cl4(3,5-diphenyl-4-amino-1,2,4-triazole)2] 、 丙酮 以 N,N-二甲基甲酰胺 、 丙酮 为溶剂， 生成 [CuCl2(3,5-diphenyl-4-isopropylidenoamino-1,2,4-triazole)2]
  参考文献：
  名称：

  Cu(II) and Co(II) complexes with 3,5-diphenyl-4-amino-1,2,4-triazole: Synthesis and study

  摘要：

  The Cu(II) and Co(II) complexes with 3,5-diphenyl-4-amino-1,2,4-triazole (L) of the composition CuLA(2)center dot H2O (A = Cl-, Br-), CuL(2)A(2) (A = Cl-, Br-, NO3-), CoL(2)A(2)center dot nH(2)O (A = Cl-, n = 1; A = NCS-, n = 0) are synthesized. In these complexes, the ligand L is coordinated to a metal in monodentate mode through the heterocyclic N(1) atom. The Cu:L = 1:1 complexes have binuclear structures with the anions acting as bridges, whereas the M:L = 1:2 complexes are mononuclear. Both ferro- and antiferromagnetic exchange interactions are detected for the synthesized complexes.

  DOI：

  10.1134/s1070328406050010
• 作为产物：
  描述：

  copper(II) choride dihydrate 、 3,5-二苯基-4H-1,2,4-噻唑-4-胺 以 乙醇 、 正己烷 为溶剂， 以80%的产率得到[Cu2(H2O)2Cl4(3,5-diphenyl-4-amino-1,2,4-triazole)2]
  参考文献：
  名称：

  Cu(II) and Co(II) complexes with 3,5-diphenyl-4-amino-1,2,4-triazole: Synthesis and study

  摘要：

  The Cu(II) and Co(II) complexes with 3,5-diphenyl-4-amino-1,2,4-triazole (L) of the composition CuLA(2)center dot H2O (A = Cl-, Br-), CuL(2)A(2) (A = Cl-, Br-, NO3-), CoL(2)A(2)center dot nH(2)O (A = Cl-, n = 1; A = NCS-, n = 0) are synthesized. In these complexes, the ligand L is coordinated to a metal in monodentate mode through the heterocyclic N(1) atom. The Cu:L = 1:1 complexes have binuclear structures with the anions acting as bridges, whereas the M:L = 1:2 complexes are mononuclear. Both ferro- and antiferromagnetic exchange interactions are detected for the synthesized complexes.

  DOI：

  10.1134/s1070328406050010