| 173413-66-6

• CAS: 173413-66-6
• 化学式: C₁₇H₂₂ClO₃Rh
• 分子量: 412.718
• InChiKey: QSPURIPECHSIQY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 乙基麦芽酚 、 sodium methylate 以 甲醇 为溶剂， 以96%的产率得到
  参考文献：
  名称：

  Complexes of Rh(C5Me5) with picolinic acid, pyrones and pyridinones

  摘要：

  Picolinic acid (pyridine-2-carboxylic acid), pyrones and pyridinones (HL) reacted with [{Rh(C(5)Me(5))Cl-2}(2)] and sodium methoxide to give complexes [Rh(C(3)Me(5))Cl(L)] which are all soluble in water. The structures where HL = picolinic acid or 2-methylpyran-4-one have been determined by X-ray diffraction. The aquation of the complexes when dissolved in water has been examined by NMR spectroscopy and conductivity measurements and the results indicate an equilibrium between chloro and aqua species which is fast on the NMR time-scale.

  DOI：

  10.1039/dt9950003709