dichloro(2-formylpyridine-para-nitrophenyl hydrazone)zinc(II) | 1202794-22-6

• 英文名称: dichloro(2-formylpyridine-para-nitrophenyl hydrazone)zinc(II)
• CAS: 1202794-22-6
• 化学式: C₁₃H₁₀Cl₂N₄O₃Zn
• 分子量: 406.543
• InChiKey: FVXWOJLNFFIYKG-SFRYUHGMSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  dichloro(2-formylpyridine-para-nitrophenyl hydrazone)zinc(II) 、 二甲基亚砜 以 二甲基亚砜 、 丙酮 为溶剂， 生成 chloro(dimethylsulfoxide)(2-formylpyridine-para-nitrophenyl hydrazonato)zinc(II)
  参考文献：
  名称：

  Copper(II) and zinc(II) complexes with 2-formylpyridine-derived hydrazones

  摘要：

  In the present work 2-formylpyridine-para-chloro-phenyl hydrazone (H2FopCIPh) and 2-formylpyridine-para-nitro-phenyl hydrazone (H2FopNO(2)Ph) were obtained, as well as their copper(II) and zinc(II) complexes [Cu(H2FopClPh)Cl-2] (1), [Cu(2FopNO(2)Ph)Cl] (2), [Zn(H2FopClPh)Cl-2] (3) and [Zn(H2FopNO(2)Ph)Cl-2] (4). Upon re-crystallization in DMSO:acetone conversion of 2 into [Cu(2FopNO(2)Ph)Cl(DMSO)] (2a) and of 4 into [Zn(2FopNO(2)Ph)Cl(DMSO)] (4a) occurred. The crystal structures of 1, 2a, 3 and 4a were determined. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.07.059
• 作为产物：
  描述：

  zinc(II) chloride 、 (E)-4-nitro-N'-(pyridine-2-ylmethylene)benzohydrazide 以 乙醇 为溶剂， 以78%的产率得到dichloro(2-formylpyridine-para-nitrophenyl hydrazone)zinc(II)
  参考文献：
  名称：

  Copper(II) and zinc(II) complexes with 2-formylpyridine-derived hydrazones

  摘要：

  In the present work 2-formylpyridine-para-chloro-phenyl hydrazone (H2FopCIPh) and 2-formylpyridine-para-nitro-phenyl hydrazone (H2FopNO(2)Ph) were obtained, as well as their copper(II) and zinc(II) complexes [Cu(H2FopClPh)Cl-2] (1), [Cu(2FopNO(2)Ph)Cl] (2), [Zn(H2FopClPh)Cl-2] (3) and [Zn(H2FopNO(2)Ph)Cl-2] (4). Upon re-crystallization in DMSO:acetone conversion of 2 into [Cu(2FopNO(2)Ph)Cl(DMSO)] (2a) and of 4 into [Zn(2FopNO(2)Ph)Cl(DMSO)] (4a) occurred. The crystal structures of 1, 2a, 3 and 4a were determined. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.07.059