tribromohydroxyphosphonium hexafluoroantimonate | 412956-06-0

• 英文名称: tribromohydroxyphosphonium hexafluoroantimonate
• CAS: 412956-06-0
• 化学式: Br₃HOP*F₆Sb
• 分子量: 523.434
• InChiKey: QYXXVCZYHNBLDV-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氢氟酸 、 五氟化锑 、 三溴氧磷 以 氢氟酸 为溶剂， 生成 tribromohydroxyphosphonium hexafluoroantimonate
  参考文献：
  名称：

  Tribromohydroxyphosphonium Hexafluorometalate:  Synthesis, Spectroscopic Characterization, and Crystal Structure of Br₃POH⁺AsF₆^-

  摘要：

  The reaction of tribromophosphine oxide in the superacidic systems XF/MF5 (X = H, D; M = As, Sb) leads to tribromohydroxyphosphonium hexafluorometalates. The structure was successfully elucidated in the case of tribromohydroxyphosphonium hexafluoroarsenate. Br3POH+AsF6- crystallizes in the orthorhombic space group Pnma (No. 53 with a = 1292.5(l) pm, b = 871.6(l) pm, and c = 845.0(1) pm) with four formula units per cell. The Raman, IR, H-1 NMR, and P-31 NMR spectra of Br3POX+MF6- (X = H, D; M = As, Sb) are reported.

  DOI：

  10.1021/ic0109039