[(pentamethylcyclopentadienyl)Ru(C4H4BNCHCH2)RuCl(pentamethylcyclopentadienyl)] | 1153686-57-7

• 英文名称: [(pentamethylcyclopentadienyl)Ru(C4H4BNCHCH2)RuCl(pentamethylcyclopentadienyl)]
• CAS: 1153686-57-7
• 化学式: C₂₆H₃₇BClNRu₂
• 分子量: 611.99
• InChiKey: BZPLZWOWOWAFKJ-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  [(η(5)-pentamethylcyclopentadienyl)RuCl]4 、 1,2-dihydro-2-vinyl-1,2-azaborine-1-yllithium 以 四氢呋喃 为溶剂， 以85%的产率得到[(pentamethylcyclopentadienyl)Ru(C4H4BNCHCH2)RuCl(pentamethylcyclopentadienyl)]
  参考文献：
  名称：

  The ligand properties of 2-vinyl-1,2-azaboratabenzene

  摘要：

  Lithium 2-vinyl-1,2-azaboratabenzene 1b has been prepared by a multistep synthesis from 2,2-dibutyl-2,5-dihydro-1-trimethylsilyl-1H-1,2-azastannole 6. The reaction of 1b with one equivalent of [Cp*RuCl](4) gave the very labile sandwich compound 11. However, the reaction of 1b with 2 equiv. of [Cp*RuCl](4) afforded the stable diruthenium complex 12. The X-ray structure of 12 shows that the first Cp*Ru moiety is pi-bound to the 1,2-azaboratabenzene ring while the second is bound to Cl and to the nitrogen and the pendant B-vinyl of the 1,2-azaboratabenzene group. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.10.043