(η5-cyclopentadienyl)(η2-ethylene)phenylnickel | 86188-83-2

• 英文名称: (η5-cyclopentadienyl)(η2-ethylene)phenylnickel
• 英文别名: (η(5)-C5H5)Ni(Ph)(η(2)-CH2=CH2)
• CAS: 86188-83-2
• 化学式: C₁₃H₁₄Ni
• 分子量: 228.944
• InChiKey: YIMQGUFONLEOAP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η5-cyclopentadienyl)(η2-ethylene)phenylnickel 、 乙烯 以 氘代四氢呋喃 为溶剂， 生成 (η5-cyclopentadienyl)(syn-(7-methyl-1,2,7-η3-benzyl))nickel
  参考文献：
  名称：

  Lehmkuhl, Herbert; Keil, Thomas; Benn, Reinhard, Chemische Berichte, 1988, vol. 121, p. 1931 - 1940

  摘要：

  DOI：
• 作为产物：
  描述：

  乙烯 、 nickelocene 在 PhLi 作用下， 以 not given 为溶剂， 生成 (η5-cyclopentadienyl)(η2-ethylene)phenylnickel
  参考文献：
  名称：

  The activation of C-H bonds in terminal olefins by cyclopentadienylnickel species

  摘要：

  The alkylidynetrinickel clusters (NiCp)(3)C(CH2)(8)CH3 1, (NiCp)(3)CCH3 2 and tetrakis(eta(5)-cyclopentadienyl)dihydrido (NiCp)(4)H-2 3 were isolated from the reaction mixture of nickelocene with phenyllithium in the presence of 1-decene. (NiCp)(3)C(CH2)(4)CH3 and the clusters 2 and 3 were obtained in reaction with 1-hexene. In the presence of 2,4,4-trimethyl-1-pentene, cluster 3 was obtained as the main product of the reaction.In the reaction with 1-decene, organic products (olefins, biphenyl, o-terphenyl, quartephenyl) were identified by GC/MS analyses. The structure of 3 has been determined by X-ray diffraction and characterized by H-1 and C-13 NMR, MS and LR. On the basis of organonickel and organic products formed, the mechanism of the sp(2)-hybridized C-H bond activation by cyclopentadienylnickel species has been discussed. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(96)06777-0

文献信息

• Lehmkuhl, Herbert; Naydowski, Christian; Danowski, Friedhelm, Chemische Berichte, 1984, vol. 117, # 11, p. 3231 - 3254
  作者：Lehmkuhl, Herbert、Naydowski, Christian、Danowski, Friedhelm、Bellenbaum, Marita、Benn, Reinhard、et al.

  DOI：——

  日期：——
• NiC-addition an komplexiertes alken
  作者：Herbert Lehmkuhl、Christian Naydowskip、Reinhard Benn、Anna Rufińska、Gerhard Schroth

  DOI：10.1016/s0022-328x(00)98659-5

  日期：1983.4
• LEHMKUHL, HERBERT;KEIL, THOMAS;BENN, REINHARD;RUFINSKA, ANNA;KRUGER, CARL+, CHEM. BER., 121,(1988) N 11, C. 1931-1940
  作者：LEHMKUHL, HERBERT、KEIL, THOMAS、BENN, REINHARD、RUFINSKA, ANNA、KRUGER, CARL+

  DOI：——

  日期：——