| 1318778-53-8

• CAS: 1318778-53-8
• 化学式: C₃₇H₅₃CoN₂O₂
• 分子量: 616.833
• InChiKey: OXAULFHPXJQRLX-YDRIMNBDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  一氧化碳 、 (2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)Co 以 正己烷 为溶剂， 以87%的产率得到
  参考文献：
  名称：

  A Masked Two-Coordinate Cobalt(I) Complex That Activates C–F Bonds

  摘要：

  We report the isolation, characterization, and reactions of the unsaturated complex (LCo)-Co-tBu (L-tBu = bulky beta-diketiminate ligand). The unusual slipped kappa N,eta(6)-arene binding mode in (LCo)-Co-tBu interconverts rapidly and reversibly with the traditional kappa N-2,N' ligation mode upon binding of Lewis bases, making it a "masked" two-coordinate complex. The mechanism of this isomerization is demonstrated using kinetic studies. (LCo)-Co-tBu is a stable yet reactive synthon for low-coordinate cobalt(I) complexes and is capable of cleaving the C-F bond in fluorobenzene.

  DOI：

  10.1021/ja2052914