| 627546-60-5

• CAS: 627546-60-5
• 化学式: C₄₈H₅₂Au₂B₁₀O₆P₂
• 分子量: 1288.93
• InChiKey: FLNNMELSTNJUHN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 以 二氯甲烷 、 正戊烷 为溶剂， 生成
  参考文献：
  名称：

  Alkynyl Gold(I) Rigid-Rod Molecules from 1,12-Bis(ethynyl)-1,12-dicarba-closo-dodecaborane(12)

  摘要：

  Reactions of 1,12-bis(ethynyl)-1,12-dicarba-closo-dodecaborane(12), 1,12-(HCdropC)(2)-1,12-C2B10H10 (diethynylcarborane, decH(2)), with gold complexes of type [Au(acac)L] (acac = acetylacetonate) gave the neutral digold complexes [(AuL)(2)(mu-dec)] [L = PPh3 (1), P(C6H4-OMe-4)(3) (2), C((NHBu)-Bu-t)(NEt2) (3)]. The neutral complex [((AuCNBu)-Bu-t)(2)(mu-dec)] (5) was obtained by adding (BuNC)-Bu-t to the complex [Au-2(mu-dec)](n) (4) resulting from the reaction of decH(2) with [AuCl(SMe2)] and NEt3. The anionic complex PPN[Au(decH)(2)] (6) (PPN = Ph3P=N=PPh3) was isolated from its mixture with (PPN)(2)[{Au(decH)}(2)(mu-dec)] (7) by reacting PPN[Au(acac)(2)] and decH(2) in 1:4 molar ratio. The rigid-rod structures of the digold compound 2.CH2Cl2 and the salt 6.CHCl3 were determined by X-ray crystallography.

  DOI：

  10.1021/om0304311
• 作为产物：
  描述：

  1,12-bis(ethynyl)-1,12-dicarba-closo-dodecaborane(12) 、 Au(acetylacetonate)(P(C6H4OMe-4)3) 以 丙酮 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  Alkynyl Gold(I) Rigid-Rod Molecules from 1,12-Bis(ethynyl)-1,12-dicarba-closo-dodecaborane(12)

  摘要：

  Reactions of 1,12-bis(ethynyl)-1,12-dicarba-closo-dodecaborane(12), 1,12-(HCdropC)(2)-1,12-C2B10H10 (diethynylcarborane, decH(2)), with gold complexes of type [Au(acac)L] (acac = acetylacetonate) gave the neutral digold complexes [(AuL)(2)(mu-dec)] [L = PPh3 (1), P(C6H4-OMe-4)(3) (2), C((NHBu)-Bu-t)(NEt2) (3)]. The neutral complex [((AuCNBu)-Bu-t)(2)(mu-dec)] (5) was obtained by adding (BuNC)-Bu-t to the complex [Au-2(mu-dec)](n) (4) resulting from the reaction of decH(2) with [AuCl(SMe2)] and NEt3. The anionic complex PPN[Au(decH)(2)] (6) (PPN = Ph3P=N=PPh3) was isolated from its mixture with (PPN)(2)[{Au(decH)}(2)(mu-dec)] (7) by reacting PPN[Au(acac)(2)] and decH(2) in 1:4 molar ratio. The rigid-rod structures of the digold compound 2.CH2Cl2 and the salt 6.CHCl3 were determined by X-ray crystallography.

  DOI：

  10.1021/om0304311