| 42765-77-5

• CAS: 42765-77-5
• 化学式: C₇H₈Br₂Pd
• 分子量: 358.369
• InChiKey: ZOXWBRWFLJXGLP-HBJFUXGYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,1'-双(二苯基膦)二茂铁 、 以 丙酮 为溶剂， 以95%的产率得到[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) bromide, Pd 12.9%
  参考文献：
  名称：

  Synthesis, X-ray, spectroscopic and a preliminary Suzuki coupling screening studies of a complete series of dppfMX2 (M=Pt, Pd; X=Cl, Br, I)

  摘要：

  A complete series of dppfMX(2) (M = Pt, Pd; X = Cl, Br, I) compounds have been synthesized using different routes, and characterized fully. The synthesis of dppfPdI, has been achieved by reacting Pd(COD)Cl-2 with dppf in the presence of NaI. X-ray structures of dppfPdBr(2) and dppfPdI(2) have also been reported for the first time in this study. A preliminary Suzuki coupling screening study reveals that dppfPdX(2), compounds are superior to the conventional Ph3P-based catalysts and bidentate phosphine-based ligands. Reactions carried out under in situ conditions also gave a similar trend, but their respective activities were much lower than that of the fully formed catalysts. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00981-0

文献信息

• Mason; Duff; Miller, Inorganic Chemistry, 1992, vol. 31, # 13, p. 2746 - 2755
  作者：Mason、Duff、Miller、Jacobson、Verkade

  DOI：——

  日期：——