[iron(II) (chloride)2 (2-propanol)4] | 685569-57-7

• 英文名称: [iron(II) (chloride)2 (2-propanol)4]
• 英文别名: [FeCl2(HOPr(i))4]
• CAS: 685569-57-7；837387-40-3
• 化学式: C₁₂H₃₂Cl₂FeO₄
• 分子量: 367.137
• InChiKey: PYIRVGRIWNHAHE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [iron(II) (chloride)2 (2-propanol)4] 以 异丙醇 为溶剂， 生成 铁粉
  参考文献：
  名称：

  Fe（II）在2-丙醇中的辐射还原

  摘要：

  通过脉冲辐射分解技术研究了铁（II）在2-丙醇中的第一步还原步骤。溶剂化电子与铁（II）的反应的速率常数为4.8×10 9  dm 3  mol -1  s -1。确定了Fe（I）在350 nm处的最大吸收光谱。Fe II在惰性气氛下在2-丙醇中的辐射还原导致形成非常小的铁纳米颗粒，而在CO气氛下则形成稳定的Fe（CO）5络合物。

  DOI：

  10.1016/j.cplett.2006.09.055
• 作为产物：
  描述：

  iron(II) chloride 、 [V(OiPr)₄]₂ 以 not given 为溶剂， 生成 [iron(II) (chloride)2 (2-propanol)4]
  参考文献：
  名称：

  The first hetero-binuclear alkoxide of iron and vanadium: structural and spectroscopic features

  摘要：

  The immediate reaction between [V-2(mu-OPri)(2)(OPri)6] (A) and [Fe-2(mu-I)(2)I-2(HOPri)(4)] (B) in toluene/propan-2-ol gives the novel mixed-metal [FeI2(mu-OPri)(2)V(0Pr(i))(2)(HOPri)] (C). Structural, spectroscopic and magnetochemical characterisation are all consistent with a non-oxo vanadium(IV)/high-spin iron(II) formulation; variable-temperature X-band EPR spectra reveal an S = 1/2 <----> S = 1 equilibrium involving the vanadium centres in propan-2-ol solution. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(03)00250-8

文献信息

• Iron(<scp>iii</scp>) and titanium(<scp>iv</scp>) oxoalkoxide chemistry: synthetic, structural, magnetochemical and spectroscopic studies of [Ti₃(μ₃-OPrⁱ)₂(μ-OPrⁱ)₃(OPrⁱ)₆][FeCl₄] and [Fe₅(μ₅-O)(μ-OPrⁱ)₈Cl₅]
  作者：Dayane M. Reis、Giovana G. Nunes、Eduardo L. Sá、Geraldo R. Friedermann、Antonio S. Mangrich、David J. Evans、Peter B. Hitchcock、G. Jeffery Leigh、Jaísa F. Soares

  DOI：10.1039/b403899a

  日期：——

  Two synthetic routes were employed for the preparation of iron(III) haloalkoxides in the presence of titanium(IV). Three crystalline products (A, B and C) were isolated and characterised by chemical and physical techniques including X-ray diffractometry, Mössbauer and EPR spectroscopies and variable-temperature magnetic susceptibility measurements. Products B and C are common to both synthetic routes

  在钛（IV）存在下，采用两种合成途径制备卤代铁（III）的卤化物。分离出三种结晶产物（A，B和C）并通过化学和物理技术进行了表征，包括X射线衍射，Mössbauer和EPR光谱学和可变温度磁化率测量。产物B和C对于两种合成路线都是共同的。产品A是单核铁（II）络合物，反式-[FeCl 2（HOPr i）4 ]，可能是通过氧化丙-2-醇通过FeCl 3在反应介质中。乙是离子，混合金属钛[Ti 3（μ 3 -OPr我）2（μ-OPR我）3（OPR我）6 ] [的FeCl 4 ]，而Ç是一种高收率氧代haloalkoxide，[铁5（μ 5 -O）（μ-OPR我）8氯5 ]。在[ 2 H 8 ]-四氢呋喃溶液中从323至173 K的磁矩测量结果表明，C中含有反铁磁耦合的铁（III）处于中间（S = 3/2）自旋配置的中心。C是固态的多晶型物，在单斜晶系或四方晶系中分别结晶为非溶剂化物和单溶剂化物
• New FeII starting materials: preparation, characterisation and structural features of iron halide complexes with alcohol ligands
  作者：Giovana G Nunes、Rúbia C.R Bottini、Dayane M Reis、Pedro H.C Camargo、David J Evans、Peter B Hitchcock、G Jeffery Leigh、Eduardo L Sá、Jaı́sa F Soares

  DOI：10.1016/j.ica.2003.10.004

  日期：2004.3

  The new mononuclear [FeCl2(HOPri)(4)] (1), polymeric [Cl3Fe(mu-Cl)Fe(HOPri)(4)}(n)] (2) and binuclear [I2Fe(mu-I)(2)Fe((PrOH)-O-i)(4)] (3) iron(II) complexes have been synthesized in high yields in propan-2-ol or toluene/propan-2-ol mixtures at room temperature. Magnetic moment measurements, Fe-57 Mossbauer spectroscopy data and the results of semi-empirical quantum mechanical calculations confirmed the high-spin configuration of the iron(II) centres, which were shown to be four- and/or six-coordinate by single crystal X-ray diffraction analyses. Intermolecular hydrogen bonding was observed in the solid state structure of 1, intramolecular interactions in 2, while both intra- and intermolecular association was seen in 3. Long iron-(mu-halide) bonds suggest the possibility of complex dissociation in solution and facile ligand substitution in 2 and 3. (C) 2003 Elsevier B.V. All rights reserved.