iron monocarbonyl anion | 71765-17-8

• 英文名称: iron monocarbonyl anion
• CAS: 71765-17-8
• 化学式: CFeO
• 分子量: 83.8574
• InChiKey: RDECNZZOBWCBAS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  三羰基(四苯基环戊二烯酮)铁 、 iron monocarbonyl anion 以 二氯甲烷 为溶剂， 生成 四苯基环戊二烯酮 、
  参考文献：
  名称：

  铁和钌桥式络合物的电化学

  摘要：

  DOI：

  10.1021/om00092a008
• 作为产物：
  描述：

  [Na(THF)2][Zn(Fe(CO)4)2] 在 NiCl₂ 作用下， 以 四氢呋喃 为溶剂， 生成 iron monocarbonyl anion
  参考文献：
  名称：

  Sosinsky, Barrie A.; Shong, Robert G.; Fitzgerald, Brian J., Inorganic Chemistry, 1983, vol. 22, # 21, p. 3124 - 3129

  摘要：

  DOI：

文献信息

• Reactions of laser-ablated iron atoms and cations with carbon monoxide: Infrared spectra of FeCO+, Fe(CO)2+, Fe(CO)x, and Fe(CO)x− (x=1–4) in solid neon
  作者：Mingfei Zhou、Lester Andrews

  DOI：10.1063/1.478970

  日期：1999.6

  Laser-ablated iron atoms, cations, and electrons have been reacted with CO molecules during condensation in excess neon. The FeCO molecule is observed at 1933.7 cm−1 in solid neon. Based on isotopic shifts and density functional calculations, the FeCO molecule has the same Σ−3 ground state in solid neon that has been observed at 1946.5 cm−1 in a recent high resolution gas phase investigation [Tanaka et al., J. Chem. Phys. 106, 2118 (1997)]. The C–O stretching vibration of the Fe(CO)2 molecule is observed at 1917.1 cm−1 in solid neon, which is in excellent agreement with the 1928.2 cm−1 gas phase value for the linear molecule. Anions and cations are also produced and trapped, absorptions at 1782.0, 1732.9, 1794.5, and 1859.7 cm−1 are assigned to the linear FeCO−, Fe(CO)2−, trigonal planar Fe(CO)3−, and C3v Fe(CO)4− anions, respectively, and 2123.0, 2134.0 cm−1 absorptions to the linear FeCO+ and Fe(CO)2+ cations. Doping these experiments with CCl4 virtually eliminates the anion absorptions and markedly increases the cation absorptions, which confirms the charge identifications. Higher iron carbonyl Fe(CO)3, Fe(CO)4, and Fe(CO)5 absorptions are produced on photolysis.
• Infrared spectroelectrochemical observation of the reduction of iron pentacarbonyl
  作者：David J. Curran、Philip B. Graham、Marvin D. Rausch

  DOI：10.1021/om00030a058

  日期：1993.6

  The electrochemical reduction of iron pentacarbonyl was studied using infrared spectra collected simultaneously with the electrochemical conversion. Evidence for a mechanism proceeding through the iron tetracarbonyl dianion is observed.
• Lapidus; Savel'ev; Sominskii, Kinetics and Catalysis, <hi>1984</hi>, vol. 25, # 3 pt 1, p. 538 - 541
  作者：Lapidus、Savel'ev、Sominskii、Tsapkina

  DOI：——

  日期：——