4-[2-oxo-2-(p-methoxyphenyl)]ethyliden-2,2,2,3,3,3-hexacarbonyl-1-methyl-3-mercapto-1-oxo-2,3-diferra-1-thicyclebutane | 688025-44-7

• 英文名称: 4-[2-oxo-2-(p-methoxyphenyl)]ethyliden-2,2,2,3,3,3-hexacarbonyl-1-methyl-3-mercapto-1-oxo-2,3-diferra-1-thicyclebutane
• CAS: 688025-44-7
• 化学式: C₁₈H₁₄Fe₂O₉S₂
• 分子量: 550.13
• InChiKey: XNBURKDEPZFYPC-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  diiron nonacarbonyl 、 3-methylmercapto-3'-oxomethylmercapto-1-(p-methoxyphenyl)-2-propen-1-one 以 四氢呋喃 为溶剂， 以12%的产率得到4-[2-oxo-2-(p-methoxyphenyl)]ethyliden-2,2,2,3,3,3-hexacarbonyl-1-methyl-3-mercapto-1-oxo-2,3-diferra-1-thicyclebutane
  参考文献：
  名称：

  Novel dinuclear iron(0) complexes from α,β-unsaturated ketones β-positioned with sulfide and sulfoxide groups

  摘要：

  The reaction of Fe-2(CO)(9) with alpha,beta-unsaturated ketones analogues containing beta-positioned sulfoxide group 2a-2d afforded di-nuclear Fe(0) complexes 3a-3d and 5 which were characterized by IR, mass spectrometry, H-1 and C-13 NMR spectroscopy, the structures of 3a, 3c and 5 were established by X-ray diffraction analysis. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.12.015