methyl[2-[(phenylimino-κN)methyl]phenyl-κC](carbonyl)bis(trimethylphosphine)iron(II) | 1140507-72-7

• 英文名称: methyl[2-[(phenylimino-κN)methyl]phenyl-κC](carbonyl)bis(trimethylphosphine)iron(II)
• CAS: 1140507-72-7
• 化学式: C₂₁H₃₁FeNOP₂
• 分子量: 431.278
• InChiKey: PJQIEYZHLITTCL-FOGCBLJHSA-N

反应信息

• 作为产物：
  描述：

  一氧化碳 、 methyl[2-[(phenylimino-κN)methyl]phenyl-κC]tris(trimethylphosphine)iron(II) 以 正戊烷 为溶剂， 以73%的产率得到methyl[2-[(phenylimino-κN)methyl]phenyl-κC](carbonyl)bis(trimethylphosphine)iron(II)
  参考文献：
  名称：

  C−H Activation of Imines by Trimethylphosphine-Supported Iron Complexes and Their Reactivities

  摘要：

  First examples of ortho-metalated mono-iron complexes of monodentate N-donor ligands via C-H activation have been synthesized. Treatment of benzylicimines and ketimines with Fe(CH3)(2)(PMe3)(4) and Fe(PMe3)(4) under mild conditions results in ortho-metalated hydrido-iron(II) and methyl-iron(II) complexes in high yields, and their iodomethane reactions give thermally stable iodo-iron(II) compounds, which are interesting versatile nucleophiles in organometallic and organic chemistry.

  DOI：

  10.1021/om800828j

文献信息

• C−Cl Bond Activation of <i>ortho</i>-Chlorinated Imine with Iron Complexes in Low Oxidation States
  作者：Yujie Shi、Min Li、Qingping Hu、Xiaoyan Li、Hongjian Sun

  DOI：10.1021/om801162u

  日期：2009.4.13

  The ortho-chelated iron(II) complexes [FeCl(PMe3)3((C6H3Cl-ortho)CH═N-R)] (R = Me, Ph) (3, 4) and [FeCl(PMe3)3(C6H4-CH═N-R)] (R = Ph, n-Bu) (7, 8) were prepared through oxidative addition of the C−Cl bond of ortho-chlorinated imine using iron(0) complexes, [Fe(PMe3)4]. The reactions of 3, 4, and 8 with CO delivered the carbonyl Fe(II) complexes 9−11. A one-pot reaction of [FeMe2(PMe3)4] with (C6H3Cl2-2

  的邻位-chelated铁（II）配合物[的FeCl（PME 3）3（（C 6 H ^ 3氯离子邻位）CH═NR）]（R = Me中，PH）（3，4）和[的FeCl（PME 3）3（C 6 H ^ 4 -CH═NR）〕（R =苯基，ñ -Bu）（7，8）通过氧化加成的C-Cl键的制备邻-chlorinated亚胺使用铁（0）配合物，[ Fe（PMe 3）4 ]。的反应3，4，和8用CO输送的羰基铁（II）配合物9 - 11。[FeMe 2（PMe 3）4 ]与（C 6 H 3 Cl 2 -2,6）CH═N-Ph在CO气氛中的一锅反应生成羰基Fe（II）络合物[FeMe（CO）（ PMe 3）2（（（C 6 H 3 Cl-邻）CH═N-Ph）]（12）。晶体和配合物的分子结构3，4，7 - 9，和12是由X射线衍射测定。