| 170958-67-5

• CAS: 170958-67-5
• 化学式: C₁₂H₁₅ClN₂Pt
• 分子量: 417.798
• InChiKey: HANHWDPFXJXEOE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三甲基氯硅烷 、 dimethyl(2,2'-bipyridine)platinum(II) 、 水 以 二氯甲烷-D2 为溶剂， 生成
  参考文献：
  名称：

  Alkyl(hydrido)platinum(IV) Complexes: The Mechanism of Pt-C Bond Protonolysis

  摘要：

  The complexes [PtMe(2)(N-N)] {N-N = (t)bu(2)-bpy (4,4'-di-tert-butyl-2,2'-bipyridine), bpy (2,2'-bipyridine), or phen (1,10-phenanthroline)} react with HX(X = Cl, Br, I, O2CCF3, SO3CF3) to yield [PtXMe(N-N)] and CH4, by an oxidative addition/reductive elimination mechanism. The new alkyl(hydrido)platinum(IV) intermediates [PtCl(H)Me(2)((t)bu(2)bpy)])] (1), [PtBr(H)Me(2)((t)bu(2)bpy)] (2), [PtH(I)Me(2)((t)bu(2)bpy)] (3), and [Pt(Cl(H)Me(2)(bpy)], (4), formed by trans oxidative addition of HX; have been fully characterized at -78 degrees C by H-1 NMR spectroscopy. Rapid reductive elimination of CH4 ensues at higher temperatures to yield the corresponding organoplatinum(II) products [PtXMe(N-N)]; The thermal stability of the platinum(IV) intermediates follows the sequence X = Cl > Br > I > O2CCF3, SO3CF3.

  DOI：

  10.1021/om00010a073