[bis(mu.-acetato)di(chloro(di(1-naphthyl)methylarsine)palladium(II))] | 855759-83-0

• 英文名称: [bis(mu.-acetato)di(chloro(di(1-naphthyl)methylarsine)palladium(II))]
• CAS: 855759-83-0
• 化学式: C₄₆H₄₀As₂Cl₂O₄Pd₂
• 分子量: 1090.41
• InChiKey: TZPVVPQQLNNFFT-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Methyl-di-[1]naphthyl-arsin 以 二氯甲烷 、 丙酮 、 苯 为溶剂， 生成 [bis(mu.-acetato)di(chloro(di(1-naphthyl)methylarsine)palladium(II))]
  参考文献：
  名称：

  Synthesis, spectroscopy, structure and photophysical properties of dinaphthylmethylarsine complexes of palladium(II) and platinum(II)

  摘要：

  Dinaphthylmethylarsine complexes of palladium(II) and platinum(II) with the formulae [MX2L2] (M = Pd, Pt; L = di(I-naphthyl)methylarsine = NaP2AsMe and X = Cl, Br, I), [M2Cl2(mu-Cl)(2)L-2], [PdCl(S2CNEt2)L], [Pd2Cl2(mu-OAc)(2)L-2] and [MCl2(PR3)L] (PR3 = PEt3, PPr3, PBu3, PMePh2) have been prepared. These complexes have been characterized by elemental analyses, IR, Raman, NMR (H-1, C-13, P-31) and UV-vis spectroscopy. The stereochemistry of the complexes has been deduced from the spectroscopic data. The crystal structures of trans-[PdCl2(PEt3)(NaP2AsMe)] and of [Pd(S2CNEt2)(2)], a follow-up product, were determined. The UV-vis spectra of [MX2L2] complexes show a red shift on going from X = Cl to X = L The complexes [PdX2L2] and [PtX2L2] are strongly luminescent in fluid solution and in the solid at ambient temperature. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.03.026