[Mn2(N,N’-bis(salicylidene)ethane-1,2-diamine(-2H))2(thiocyanate)2] | 1448551-28-7

• 英文名称: [Mn2(N,N’-bis(salicylidene)ethane-1,2-diamine(-2H))2(thiocyanate)2]
• 英文别名: [Mn₂(N,N’-bis(salicylidene)ethane-1,2-diamine(-2H))₂(thiocyanate)₂]
• CAS: 1448551-28-7
• 化学式: C₃₈H₃₆Mn₂N₆O₄S₂
• 分子量: 814.75
• InChiKey: QOYLAVSDQHRBDE-GNTHXABGSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  硫氰酸铵 、 bis-(5-methyl-salicylidene)-ethylenediamine 、 manganese (II) acetate tetrahydrate 在 air 作用下， 以 甲醇 为溶剂， 反应 0.33h， 以37%的产率得到[Mn2(N,N’-bis(salicylidene)ethane-1,2-diamine(-2H))2(thiocyanate)2]
  参考文献：
  名称：

  Synthesis, crystal structures, and catalytic properties of phenoxo-bridged dinuclear manganese(III) complexes with bis-Schiff bases

  摘要：

  Two structurally similar centrosymmetric phenoxo-bridged dinuclear manganese(III) complexes, [Mn-2(L-1)(2)(N-3)(2)] (1) and [Mn-2(L-2)(2)(NCS)(2)] (2), were prepared from the tetradentate bis-Schiff base ligands, N,N'-bis(salicylidene)propane-1,2-diamine (H2L1) and N,N'-bis(salicylidene)ethane-1,2-diamine (H2L2), respectively, in the presence of pseudohalides. The complexes have been characterized by FTIR, elemental analyses, and molar conductivity. Structures of the complexes have been confirmed by single-crystal X-ray determination. The bis-Schiff base ligands coordinate with Mn through their phenolate oxygen and imino nitrogen. Each Mn is an octahedral. The complexes showed that they exhibit high activity in catalytic olefin oxidation.

  DOI：

  10.1080/00958972.2013.811495
• 作为试剂：
  描述：

  3-甲基-1-环己烯 在 [Mn2(N,N’-bis(salicylidene)ethane-1,2-diamine(-2H))2(thiocyanate)2] 、 双氧水 、 碳酸氢钠 作用下， 以 水 、 乙腈 为溶剂， 生成 1-甲基-1,2-环氧环己烷
  参考文献：
  名称：

  Synthesis, crystal structures, and catalytic properties of phenoxo-bridged dinuclear manganese(III) complexes with bis-Schiff bases

  摘要：

  Two structurally similar centrosymmetric phenoxo-bridged dinuclear manganese(III) complexes, [Mn-2(L-1)(2)(N-3)(2)] (1) and [Mn-2(L-2)(2)(NCS)(2)] (2), were prepared from the tetradentate bis-Schiff base ligands, N,N'-bis(salicylidene)propane-1,2-diamine (H2L1) and N,N'-bis(salicylidene)ethane-1,2-diamine (H2L2), respectively, in the presence of pseudohalides. The complexes have been characterized by FTIR, elemental analyses, and molar conductivity. Structures of the complexes have been confirmed by single-crystal X-ray determination. The bis-Schiff base ligands coordinate with Mn through their phenolate oxygen and imino nitrogen. Each Mn is an octahedral. The complexes showed that they exhibit high activity in catalytic olefin oxidation.

  DOI：

  10.1080/00958972.2013.811495