methyl[2-[(methylimino-κN)methyl]phenyl-κC](carbonyl)bis(trimethylphosphine)iron(II) | 1140507-70-5

• 英文名称: methyl[2-[(methylimino-κN)methyl]phenyl-κC](carbonyl)bis(trimethylphosphine)iron(II)
• CAS: 1140507-70-5
• 化学式: C₁₆H₂₉FeNOP₂
• 分子量: 369.207
• InChiKey: WEISMBRTXIOMKX-RRVUUBHJSA-N

物化性质

• 熔点：
  134-136 °C

反应信息

• 作为产物：
  描述：

  一氧化碳 、 methyl[2-[(methylimino-κN)methyl]phenyl-κC]tris(trimethylphosphine)iron(II) 以 正戊烷 为溶剂， 以66%的产率得到methyl[2-[(methylimino-κN)methyl]phenyl-κC](carbonyl)bis(trimethylphosphine)iron(II)
  参考文献：
  名称：

  C−H Activation of Imines by Trimethylphosphine-Supported Iron Complexes and Their Reactivities

  摘要：

  First examples of ortho-metalated mono-iron complexes of monodentate N-donor ligands via C-H activation have been synthesized. Treatment of benzylicimines and ketimines with Fe(CH3)(2)(PMe3)(4) and Fe(PMe3)(4) under mild conditions results in ortho-metalated hydrido-iron(II) and methyl-iron(II) complexes in high yields, and their iodomethane reactions give thermally stable iodo-iron(II) compounds, which are interesting versatile nucleophiles in organometallic and organic chemistry.

  DOI：

  10.1021/om800828j