| 1196204-96-2

• CAS: 1196204-96-2
• 化学式: C₁₉H₂₅Br₂N₅OZn
• 分子量: 564.638
• InChiKey: ZEFRPZNGZIGVON-RGFWRHHQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-[1-methoxy(1-methyl-1H-imidazol-2-yl)(1-methyl-5-tert-butylpyrazol-3-yl)methyl]pyridine 、 zinc dibromide 以 四氢呋喃 为溶剂， 以62%的产率得到
  参考文献：
  名称：

  Zinc complexes of a tripodal ligand containing three different N-heterocyclic donor functions

  摘要：

  The coordination chemistry of a chiral tripodal ligand L containing pyridyl, imidazolyl and pyrazolyl donor functions has been investigated in combination with zinc(II). While the reaction of a racemic mixture of L with ZnX2 (X = Cl, Br) leads to complexes LZnX2 with tetrahedrally coordinated zinc centres (the pyridyl donor function remains pending), the employment of Zn(ClO4)(2) leads to the sandwich complex [L2Zn](ClO4)(2) which due to the two possible configurations for L (S and R) occurs in form of two diastereomers (the meso form and the enantiomeric pair SS/RR). The crystal structures of all three compounds are discussed. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.07.007