[(η5-C5Me5)2Eu(t-BuNC(H)C(H)NBu-t)] | 914607-04-8

• 英文名称: [(η5-C5Me5)2Eu(t-BuNC(H)C(H)NBu-t)]
• CAS: 914607-04-8
• 化学式: C₃₀H₅₀EuN₂
• 分子量: 590.7
• InChiKey: FDJQHIBWPAOKRF-ASNJXXDOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Eu(η5-C5Me5)2(OEt2)] 、 N,N'-二丁基-1,2-乙二亚胺 以 甲苯 为溶剂， 以89%的产率得到[(η5-C5Me5)2Eu(t-BuNC(H)C(H)NBu-t)]
  参考文献：
  名称：

  Mediating Oxidation States in Decamethyleuropocene Complexes. The Role of the Diazabutadiene Fragment

  摘要：

  The Eu diazabutadiene complexes (C5Me5)(2)Eu- DADBu-t) and (C5Me5)(2)Eu(DADC(6)F(5)) (DADBu-t = t-BuNC(H)C(H) NBu-t; DADC(6)F(5) = C6F5NC(Me)C(Me)NC6F5) have been prepared, and on the basis of characterization by X-ray crystallography, magnetic susceptibility, and H-1 NMR and IR spectroscopy, it is concluded that the Eu oxidation states in these complexes are + 2 and + 3, respectively. In the case of (C5Me5)(2)Eu(DADC(6)F(5)), the internal redox process is solvent sensitive.

  DOI：

  10.1021/om060793j