[Pt(3,5-bis(2-pyridoxy)-2-dodecylbenzeneato)Cl] | 761456-94-4

• 英文名称: [Pt(3,5-bis(2-pyridoxy)-2-dodecylbenzeneato)Cl]
• CAS: 761456-94-4
• 化学式: C₂₈H₃₅ClN₂O₂Pt
• 分子量: 662.131
• InChiKey: YRBJUMQXFAWTCU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pt(3,5-bis(2-pyridoxy)-2-dodecylbenzeneato)Cl] 、 lithium perchlorate 、 双二苯基膦甲烷 以 甲醇 、 乙腈 为溶剂， 以62%的产率得到([Pt(3,5-bis(2-pyridoxy)-2-dodecylbenzeneato)]2(μ-bis(diphenylphosphino)methane))(ClO4)2
  参考文献：
  名称：

  Synthesis, characterization and spectroscopic studies of cyclometalated platinum(II) complexes containing meta-bis(2-pyridoxy)benzene

  摘要：

  A series of mononuclear and binuclear cyclometalated platinum(II) complexes containing new terdentate meta-bis(2-pyridoxy)benzene ligands: 3,5-bis(2-pyridoxy)toluene (L1H) and 3,5-bis(2-pyridoxy)-2-dodecylbenzene (L2H): [Pt(L-1)Cl] (1), [Pt(L-2)Cl] (2), [Pt(L-1)(CH3CN)](ClO4) (3), J[Pt(L-1)](2)(mu-dppm)}(ClO4)(2) (4), {[Pt(L-2)]mu-dppm))(ClO4)(2) (5), ([Pt(L-1)](2)(mu-pyrazole))(ClO4) (6), [Pt(L-2)](2)(mu-pyrazole)}(ClO4) (7), {[Pt(L-1)12(mu-imidazole))(ClO4) (8) and {[Pt(L-2)](2)(mu-imidazole)J(ClO4) (9), have been synthesized and characterized. These ligands are coordinated to platinum(II) in a "pincer"-like manner and the presence of pyridyl donors enhances the availability of the ligand pi* orbitals for electronic transition. Spectroscopic properties of these cyclometalated complexes were studied. While the non-coplanar nature of the ligands hinders ligand-ligand and metal-metal interactions in these cyclometalated complexes, the presence of long hydrocarbon side chain on ligand L2H seems to alleviate such hindrance. Intermolecular pi-pi, and possibly Pt-Pt interactions were observed in complex 2 at high concentration. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.06.006
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 3,5-bis(2-pyridoxy)-2-dodecylbenzene 以 溶剂黄146 为溶剂， 以60%的产率得到[Pt(3,5-bis(2-pyridoxy)-2-dodecylbenzeneato)Cl]
  参考文献：
  名称：

  Synthesis, characterization and spectroscopic studies of cyclometalated platinum(II) complexes containing meta-bis(2-pyridoxy)benzene

  摘要：

  A series of mononuclear and binuclear cyclometalated platinum(II) complexes containing new terdentate meta-bis(2-pyridoxy)benzene ligands: 3,5-bis(2-pyridoxy)toluene (L1H) and 3,5-bis(2-pyridoxy)-2-dodecylbenzene (L2H): [Pt(L-1)Cl] (1), [Pt(L-2)Cl] (2), [Pt(L-1)(CH3CN)](ClO4) (3), J[Pt(L-1)](2)(mu-dppm)}(ClO4)(2) (4), {[Pt(L-2)]mu-dppm))(ClO4)(2) (5), ([Pt(L-1)](2)(mu-pyrazole))(ClO4) (6), [Pt(L-2)](2)(mu-pyrazole)}(ClO4) (7), {[Pt(L-1)12(mu-imidazole))(ClO4) (8) and {[Pt(L-2)](2)(mu-imidazole)J(ClO4) (9), have been synthesized and characterized. These ligands are coordinated to platinum(II) in a "pincer"-like manner and the presence of pyridyl donors enhances the availability of the ligand pi* orbitals for electronic transition. Spectroscopic properties of these cyclometalated complexes were studied. While the non-coplanar nature of the ligands hinders ligand-ligand and metal-metal interactions in these cyclometalated complexes, the presence of long hydrocarbon side chain on ligand L2H seems to alleviate such hindrance. Intermolecular pi-pi, and possibly Pt-Pt interactions were observed in complex 2 at high concentration. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.06.006