[Os3(CO)11(phenyldi(2-thienyl)phosphine)] | 1228458-21-6

• 英文名称: [Os3(CO)11(phenyldi(2-thienyl)phosphine)]
• CAS: 1228458-21-6
• 化学式: C₂₅H₁₁O₁₁Os₃PS₂
• 分子量: 1153.06
• InChiKey: WFJGASVQNLGUOL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Os3(CO)11(phenyldi(2-thienyl)phosphine)] 以 正辛烷 为溶剂， 以37%的产率得到[Os3(μ-H)(CO)9(μ3-phenyldi(2-thienyl)phosphine(-H))]
  参考文献：
  名称：

  Carbon–hydrogen bond activation of phenyldi(2-thienyl)phosphine at a triosmium cluster centre

  摘要：

  The phenyldi(2-thienyl)phosphine (PhPTh(2)) complexes [Os(3)(CO)(12-n)(PhPTh(2))(n)] (n = 1-3) (1-3) have been prepared. Thermolysis of 1 and either 2 or 3 in octane affords carbon-hydrogen bond activation products [Os(3)(CO)(9){mu(3)-PPhTh(C(4)H(2)S)}(mu-H)] (4) and [Os(3)(CO)(8)(PPhTh(2)){mu(3)-PPhTh(C(4)H(2)S)}(mu-H)] (5), respectively. Both exist as isomeric mixtures differing in the relative positions of phenyl and thienyl substituents with respect to the triosmium centre. The nature of the process has been confirmed by a single crystal X-ray diffraction analysis of 4. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.01.030
• 作为产物：
  描述：

  phenyldi(2-thienyl)phosphine 、 undecacarbonyl(acetonitrile)triosmium 以 二氯甲烷 为溶剂， 以87%的产率得到[Os3(CO)11(phenyldi(2-thienyl)phosphine)]
  参考文献：
  名称：

  Carbon–hydrogen bond activation of phenyldi(2-thienyl)phosphine at a triosmium cluster centre

  摘要：

  The phenyldi(2-thienyl)phosphine (PhPTh(2)) complexes [Os(3)(CO)(12-n)(PhPTh(2))(n)] (n = 1-3) (1-3) have been prepared. Thermolysis of 1 and either 2 or 3 in octane affords carbon-hydrogen bond activation products [Os(3)(CO)(9){mu(3)-PPhTh(C(4)H(2)S)}(mu-H)] (4) and [Os(3)(CO)(8)(PPhTh(2)){mu(3)-PPhTh(C(4)H(2)S)}(mu-H)] (5), respectively. Both exist as isomeric mixtures differing in the relative positions of phenyl and thienyl substituents with respect to the triosmium centre. The nature of the process has been confirmed by a single crystal X-ray diffraction analysis of 4. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.01.030