(η6-4,4'-bis(trimethylsilylethynyl)biphenyl)(η4-1,5-cyclooctadiene)ruthenium(0) | 897672-64-9

• 英文名称: (η6-4,4'-bis(trimethylsilylethynyl)biphenyl)(η4-1,5-cyclooctadiene)ruthenium(0)
• 英文别名: Ru(η6-4,4'-bis(trimethylsilylethynyl)biphenyl)(η4-COD)
• CAS: 897672-64-9
• 化学式: C₃₀H₃₈RuSi₂
• 分子量: 555.873
• InChiKey: ZHUFDWXLLUPZJW-GHDUESPLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (η6-4,4'-bis(trimethylsilylethynyl)biphenyl)(η4-1,5-cyclooctadiene)ruthenium(0) 在 四丁基氟化铵 作用下， 以 四氢呋喃 为溶剂， 以95%的产率得到(η6-4,4'-bis(ethynyl)biphenyl)(η4-1,5-cyclooctadiene)ruthenium(0)
  参考文献：
  名称：

  Synthesis and characterization of new difunctional alkynylated (η6-arene)(η4-cycloocta-1,5-diene)ruthenium(0) complexes as molecular models for organometallic polymers

  摘要：

  The new dialkynylated complexes Ru(eta(6)-DEB-Si)(eta(4)-COD), 4a, Ru(eta(6)-DEBP-Si)(eta(4)-COD), 4b1, Ru-2(eta(6),eta(6)-DEBP)(eta(4)-COD)(2), 4b2 [COD = 1,5-cyclooctadiene; DEB-Si = 1,4-bis(trimethylsilylethynyl)benzene; DEBP-Si = 4,4'-bis(trimethylsilylethynyl)biphenyl] have been synthesized by the arene exchange reaction with the complex Ru(eta(6)-naphthalene)(eta(4)-COD). The complexes Ru(eta(6)-DEB)(eta(4)- COD), 5a, and Ru(eta(6)-DEBP)(eta(4)-COD), 5b1, have been prepared by desilylation of the corresponding compounds 4a and 4b1. All the complexes have been fully characterized by means of spectroscopic techniques. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.01.058
• 作为产物：
  描述：

  (η6-naphthalene)(η4-1,5-cyclooctadiene)ruthenium(0) 、 4,4'-bis[(trimethylsilyl)ethynyl]biphenyl 以 四氢呋喃 、 乙腈 为溶剂， 以80%的产率得到(η6-4,4'-bis(trimethylsilylethynyl)biphenyl)(η4-1,5-cyclooctadiene)ruthenium(0)
  参考文献：
  名称：

  Synthesis and characterization of new difunctional alkynylated (η6-arene)(η4-cycloocta-1,5-diene)ruthenium(0) complexes as molecular models for organometallic polymers

  摘要：

  The new dialkynylated complexes Ru(eta(6)-DEB-Si)(eta(4)-COD), 4a, Ru(eta(6)-DEBP-Si)(eta(4)-COD), 4b1, Ru-2(eta(6),eta(6)-DEBP)(eta(4)-COD)(2), 4b2 [COD = 1,5-cyclooctadiene; DEB-Si = 1,4-bis(trimethylsilylethynyl)benzene; DEBP-Si = 4,4'-bis(trimethylsilylethynyl)biphenyl] have been synthesized by the arene exchange reaction with the complex Ru(eta(6)-naphthalene)(eta(4)-COD). The complexes Ru(eta(6)-DEB)(eta(4)- COD), 5a, and Ru(eta(6)-DEBP)(eta(4)-COD), 5b1, have been prepared by desilylation of the corresponding compounds 4a and 4b1. All the complexes have been fully characterized by means of spectroscopic techniques. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.01.058