[CpFe(CO)2C6H4-4-C(O)OEt] | 1083330-11-3

• 英文名称: [CpFe(CO)2C6H4-4-C(O)OEt]
• 英文别名: CpFe(C6H4COOEt-4)(CO)2
• CAS: 1083330-11-3
• 化学式: C₁₆H₁₄FeO₄
• 分子量: 326.132
• InChiKey: DMZLTVBQOIDFSO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  正丁基锂 、 [CpFe(CO)2C6H4-4-C(O)OEt] 以 四氢呋喃 为溶剂， 以77%的产率得到CpFe(CO)2C6H4-4-CBu2OH]
  参考文献：
  名称：

  Synthesis of Functionalized Aryliron Complexes by Palladium-Catalyzed Transmetalation between [CpFe(CO)₂I] and Arylzinc or Arylboron Reagents

  摘要：

  Transmetalation between [CpFe(CO)(2)I] and arylzinc reagents or arylboronic acids under palladium catalysis yields the corresponding aryliron complexes [CpFe(CO)(2)Ar]. The reactions offer easy and reliable accesses to a variety of [CpFe(CO)(2)Ar] species bearing a functionalized aryl group.

  DOI：

  10.1021/om800916r
• 作为产物：
  描述：

  dicarbonylcyclopentadienyliodoiron(II) 以 not given 为溶剂， 生成 [CpFe(CO)2C6H4-4-C(O)OEt]
  参考文献：
  名称：

  Arylation of Styrenes with Aryliron Complexes [CpFe(CO)₂Ar]

  摘要：

  Treatment of aryliron complexes [CpFe(CO)(2)Ar] with styrenes in boiling xylene affords the corresponding stilbenes. The aryliron complexes, which become active upon heating, serve as arylating agents in the reaction.

  DOI：

  10.1021/om1001952

文献信息

• Use of Aryliron Complexes [CpFe(CO)₂Ar] as Arylcarbonyl Cation Equivalents in the Reactions with Organolithium Reagents To Yield Ketones
  作者：Shigeo Yasuda、Hideki Yorimitsu、Koichiro Oshima

  DOI：10.1021/om900558a

  日期：2009.8.24

  Treatment of aryliron complexes [CpFe(CO)2Ar] with organolithium reagents RLi in THF affords the corresponding ketones RCOAr. The reaction, wherein the aryliron complexes serve as arylcarbonyl cation equivalents, would begin with nucleophilic addition of RLi to one of the carbonyl ligands to form acyliron [CpFe(CO)(RCO)Ar] without lithiation of the Cp ring.

  用有机锂试剂RLi在THF中处理芳铁配合物[CpFe（CO）2 Ar]，得到相应的酮RCOAr。该反应（其中芳铁配合物用作芳基羰基阳离子等同物）将以RLi亲核加成至羰基配体之一开始，以形成酰基丙二酮[CpFe（CO）（RCO）Ar]，而无需Cp环的锂化。