(E)-(η(5)-C5Me5)(CO)2FeP=CHN(Ph)N=C(NMe2)2 | 190730-97-3

• 英文名称: (E)-(η(5)-C5Me5)(CO)2FeP=CHN(Ph)N=C(NMe2)2
• CAS: 190730-97-3
• 化学式: C₂₄H₃₃FeN₄O₂P
• 分子量: 496.372
• InChiKey: XASJIEDKDAIENQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (E)-(η(5)-C5Me5)(CO)2FeP=CHN(Ph)N=C(NMe2)2 、 富马酸二甲酯 以 乙醚 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  Transition-Metal-Substituted Acyl Phosphanes and Phosphaalkenes. 32.¹ Transformation of an FePC Unit of a Phosphaalkene into a FePCNNC Moiety by Chain Extension through Insertion of the 1,3-Dipole (^-NN(Ar)CH⁺) of Sydnones

  摘要：

  The metallophosphaalkene (eta(5)-C5Me5)(CO)(2)FeP=C(NMe2)(2) (1) underwent reaction with sydnones 3-aryl-NNOC(O)CH (aryl = C6H5 (2a), 4-FC6H4 (2b), 4-ClC6H4 (2c), 4-BrC6H4 (2d)) to afford the novel ferriophosphaalkenes (eta(5)-C5Me5)(CO)(2)FeP=CHN(aryl)N=C(NMe2)(2) (3a-d). Compound 3a forms the [2 + 2] phosphetanyl cycloadduct 4a with dimethyl fumarate. The molecular structure of 3a was determined by single-crystal X-ray diffraction.

  DOI：

  10.1021/om9700876
• 作为产物：
  描述：

  ((η(5)-C5Me5)(CO)2FeP=C(NMe2)2) 、 3-苯雪梨酮 以 乙醚 、 二氯甲烷 为溶剂， 以61%的产率得到(E)-(η(5)-C5Me5)(CO)2FeP=CHN(Ph)N=C(NMe2)2
  参考文献：
  名称：

  Transition-Metal-Substituted Acyl Phosphanes and Phosphaalkenes. 32.¹ Transformation of an FePC Unit of a Phosphaalkene into a FePCNNC Moiety by Chain Extension through Insertion of the 1,3-Dipole (^-NN(Ar)CH⁺) of Sydnones

  摘要：

  The metallophosphaalkene (eta(5)-C5Me5)(CO)(2)FeP=C(NMe2)(2) (1) underwent reaction with sydnones 3-aryl-NNOC(O)CH (aryl = C6H5 (2a), 4-FC6H4 (2b), 4-ClC6H4 (2c), 4-BrC6H4 (2d)) to afford the novel ferriophosphaalkenes (eta(5)-C5Me5)(CO)(2)FeP=CHN(aryl)N=C(NMe2)(2) (3a-d). Compound 3a forms the [2 + 2] phosphetanyl cycloadduct 4a with dimethyl fumarate. The molecular structure of 3a was determined by single-crystal X-ray diffraction.

  DOI：

  10.1021/om9700876