mer-[RhCl3(2,6-C5H3N(CMe2NH2)2)] | 935658-64-3

• 英文名称: mer-[RhCl3(2,6-C5H3N(CMe2NH2)2)]
• 英文别名: mer-[RhCl3(2,6-bis(α-aminoisopropyl)pyridine)]
• CAS: 935658-64-3
• 化学式: C₁₁H₁₉Cl₃N₃Rh
• 分子量: 402.556
• InChiKey: ZFWOCWSESSHZJB-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氯化铑(三水) 、 2,6-bis(α-aminoisopropyl)pyridine 以 乙醇 为溶剂， 以96%的产率得到mer-[RhCl3(2,6-C5H3N(CMe2NH2)2)]
  参考文献：
  名称：

  Synthesis and exploratory coordination chemistry of the new ditertiary carbinamine ligand 2,6-bis(α-aminoisopropyl)pyridine

  摘要：

  The new pyridine-based N boolean AND N boolean AND N tridentate ligand 2,6-C5H3N(CMe2NH2)(2) (1) was synthesized by the treatment of 2,6-pyridinedicarbonitrile with an excess of the organocerium reagent in situ generated from CeCl3 and methyllithium in THF. The reaction of 1 with [RuCl2(PPh3)(3)] in THF at ambient conditions afforded (OC-6-23)-[RuCl{2,6-C5H3N(CMeNH2)(2)}(PPh3)(2)]Cl (2). The corresponding dimethyl sulfoxide complex [RuCl{2,6-C5H3N(CMe2NH2)(2)} {S(O)Me-2}(2)]Cl (3) was isolated as a mixture of the (OC-6-23) and (OC-632) stercoisonters 3a and 3b from the reaction between 1 and (OC-6-22)-[RuCl2 {S(O)Me-2}(3)(OSMe2)] in toluene at 80 degrees C. A prolonged interaction in toluene at reflux temperature gave isomerically pure 3a. The metal trichloride hydrates MCl3 - xH(2)O (M = Ru, Rh, Ir; x congruent to 2-4) produced mer-[RuCl3{2,6-C5H3N(CMe2NH2)(2)}] (M = Ru: 4; Rh: 5; Ir: 6), when combined with I in refluxing ethanol. The crystal structures of the following compounds were determined: ligand 1 and complexes 2 5 as addition compounds 2 - CH2Cl2, 3a (.) C7H8, ;4 (.) EtOH and 5 (.) 2(1)/2DMF. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.08.025