bis(μ-chloro)bis(1,1'-bis(diphenylphosphino)ferrocene)dipalladium(II) tetrafluoroborate | 112220-68-5

• 英文名称: bis(μ-chloro)bis(1,1'-bis(diphenylphosphino)ferrocene)dipalladium(II) tetrafluoroborate
• 英文别名: [Pd(μ-Cl)(η2-1,1'-bis(diphenylphosphino)ferrocene)]2[BF4]2
• CAS: 112220-68-5
• 化学式: 2BF₄*C₆₈H₅₆Cl₂Fe₂P₄Pd₂
• 分子量: 1566.14
• InChiKey: GXUPOZZSGBBKEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(μ-chloro)bis(1,1'-bis(diphenylphosphino)ferrocene)dipalladium(II) tetrafluoroborate 、 sodium 2,2,2-trifluoroacetate 、 乙腈 以 甲醇 、 乙腈 为溶剂， 生成 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 [PdCl(O2CCF3)(1,1'-bis(diphenylphosphino)ferrocene)] 、 [(1,10-bis(diphenylphosphino)ferrocene)Pd(trifluoroacetate)₂]
  参考文献：
  名称：

  Isolation and structural characterization of some stable Pd(II) carboxylate complexes supported by 1,1′-bis(diphenylphosphino) ferrocene (dppf)

  摘要：

  Although catalytically active palladium phosphine carboxylates are generally unstable, a series of such complexes are stabilized by dppf, viz. Pd(O2CR)(2)(dppt) [R = CF3 I, CF2CF3 II [1,43] CF2CF2CF3 III, CHCl2 IV, o-C6H4Cl VI, CH2CO2H VII, CH=CHCO2H VIII]. They have been spectroscopically characterized and their structures determined by X-ray single-crystal crystallography. Two derivatives viz. Pd(O4C2-O,O')(dppf) IX and PdCl(O2CPh)(dppt) X are included for comparison. They are invariably mononuclear with chelating phosphine and unidentate carboxylates. The more labile (and less basic) carboxylates tend to form complexes that are more resistive to reductive decomposition. Pd(O2CPh)(2)(dppf) V decomposes readily to PdCl2(dppf) in the presence of chlorinated solvents. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01645-5
• 作为产物：
  描述：

  (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 silver tetrafluoroborate 以 not given 为溶剂， 生成 bis(μ-chloro)bis(1,1'-bis(diphenylphosphino)ferrocene)dipalladium(II) tetrafluoroborate
  参考文献：
  名称：

  Isolation and structural characterization of some stable Pd(II) carboxylate complexes supported by 1,1′-bis(diphenylphosphino) ferrocene (dppf)

  摘要：

  Although catalytically active palladium phosphine carboxylates are generally unstable, a series of such complexes are stabilized by dppf, viz. Pd(O2CR)(2)(dppt) [R = CF3 I, CF2CF3 II [1,43] CF2CF2CF3 III, CHCl2 IV, o-C6H4Cl VI, CH2CO2H VII, CH=CHCO2H VIII]. They have been spectroscopically characterized and their structures determined by X-ray single-crystal crystallography. Two derivatives viz. Pd(O4C2-O,O')(dppf) IX and PdCl(O2CPh)(dppt) X are included for comparison. They are invariably mononuclear with chelating phosphine and unidentate carboxylates. The more labile (and less basic) carboxylates tend to form complexes that are more resistive to reductive decomposition. Pd(O2CPh)(2)(dppf) V decomposes readily to PdCl2(dppf) in the presence of chlorinated solvents. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01645-5

文献信息

• Longato, Bruno; Pilloni, Giuseppe; Valle, Giovanni, Inorganic Chemistry, 1988, vol. 27, # 5, p. 956 - 958
  作者：Longato, Bruno、Pilloni, Giuseppe、Valle, Giovanni、Corain, Benedetto

  DOI：——

  日期：——