[Ru(η3-C(CCC6H4-t-Bu)=C(H)C6H4-t-Bu)(PMe3)4]BF4 | 1188475-63-9

• 英文名称: [Ru(η3-C(CCC6H4-t-Bu)=C(H)C6H4-t-Bu)(PMe3)4]BF4
• CAS: 1188475-63-9
• 化学式: BF₄*C₃₆H₆₃P₄Ru
• 分子量: 807.666
• InChiKey: MAUAHJCQEATHFL-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [Ru(η3-C(CCC6H4-t-Bu)=C(H)C6H4-t-Bu)(PMe3)4]BF4 在 Me₂Mg 作用下， 以 四氢呋喃 为溶剂， 以55%的产率得到[Ru(C(CCC6H4-t-Bu)=C(H)C6H3-t-Bu)(PMe3)4]
  参考文献：
  名称：

  Formation of Ruthenaindenes by Cyclometalation of Ruthenium(II) Diarylbutenyne Complexes

  摘要：

  The reaction of diarylbutenynylruthenium complexes [Ru(eta(3)-C CC(6)H(4)R)=C(R')C(6)H(4)R)-(PMe(3))(4)](+) (C(6)H(4)R = C(6)H(4)R = C(6)H(4)-4-'Bu, Ph, C(6)H(4)-4-Me; R' = H, Me) with dimethylinagnesium yields the cyclometalated ruthenaidene complexes [Ru(C(C CC(6)H(4)R)=C(R')'C(6)H(3)R)(PMe(3))(4)] with ruthenium incorporated into the five-membered ring of an indene. The reaction involves the initial formation of methylruthenium complexes, which then rearrange with the elimination of methane to yield the product, The complexes [Ru(C(C CC(6)H(4)R)=C(R')C(6)H(3)R)(PMe(3))(4)] (C(6)H(4)R = C(6)H(4)-4-'Bu, R' = H; C(6)H(4)R = Ph, R' = Me) were crystallographically characterized.

  DOI：

  10.1021/om900613y
• 作为产物：
  描述：

  4-叔-丁基苯基乙炔 、 2,6-lutidinium tetrafluoroborate 、 cis-[RuMe₂(PMe₃)₄] 以 四氢呋喃 为溶剂， 以65%的产率得到[Ru(η3-C(CCC6H4-t-Bu)=C(H)C6H4-t-Bu)(PMe3)4]BF4
  参考文献：
  名称：

  Formation of Ruthenaindenes by Cyclometalation of Ruthenium(II) Diarylbutenyne Complexes

  摘要：

  The reaction of diarylbutenynylruthenium complexes [Ru(eta(3)-C CC(6)H(4)R)=C(R')C(6)H(4)R)-(PMe(3))(4)](+) (C(6)H(4)R = C(6)H(4)R = C(6)H(4)-4-'Bu, Ph, C(6)H(4)-4-Me; R' = H, Me) with dimethylinagnesium yields the cyclometalated ruthenaidene complexes [Ru(C(C CC(6)H(4)R)=C(R')'C(6)H(3)R)(PMe(3))(4)] with ruthenium incorporated into the five-membered ring of an indene. The reaction involves the initial formation of methylruthenium complexes, which then rearrange with the elimination of methane to yield the product, The complexes [Ru(C(C CC(6)H(4)R)=C(R')C(6)H(3)R)(PMe(3))(4)] (C(6)H(4)R = C(6)H(4)-4-'Bu, R' = H; C(6)H(4)R = Ph, R' = Me) were crystallographically characterized.

  DOI：

  10.1021/om900613y