trans-[Rh(CO)(pyridine)(PPh3)2]ClO4 | 55254-04-1

• 英文名称: trans-[Rh(CO)(pyridine)(PPh3)2]ClO4
• CAS: 55254-04-1
• 化学式: C₄₂H₃₅NOP₂Rh*ClO₄
• 分子量: 834.05
• InChiKey: YKFJHRFYWULHFL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  四苯硼钠 、 trans-[Rh(CO)(pyridine)(PPh3)2]ClO4 在 二硫化碳 、 三苯基膦 作用下， 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Danilina, L. I.; Iretskii, A. V.; Kukushkin, Yu. N., Koordinatsionnaya Khimiya, 1985, vol. 11, p. 736 - 740

  摘要：

  DOI：
• 作为产物：
  描述：

  Rh(ClO4)(CO)(PPh3)2 在 吡啶 作用下， 以 二氯甲烷 、 二氯甲烷-D2 为溶剂， 生成 trans-[Rh(CO)(pyridine)(PPh3)2]ClO4
  参考文献：
  名称：

  Reactions of Wilkinson's catalyst with pyridine; observation of rhodium complexes containing both pyridine and phosphine ligandst

  摘要：

  Dissolution of [RhCl(PPh3)3], Wilkinson's catalyst, in pyridine affords an efficient catalyst for the selective reductive coupling of aldehydes. The reaction requires a close balance of the hydrogenating power and alkyl coupling ability of the catalyst. The species present in the pyridine solution of Wilkinson's catalyst have been studied in order to probe the origin of this selectivity. Pyridine has been found to replace one or more of the phosphine ligands in the precursor complex to give complexes of the type [RhCl(py)x(PPh3)3-x] (py = pyridine, x = 1 or 2) and [Rh(py)x(PPh3)4-x]Cl (x = 1, 2 or 3). The reactions of these complexes with hydrogen have been shown to give cis-dihydride complexes via oxidative addition. The complex trans-[Rh(CO)(py)(PPh3)2]ClO4 has been synthesised and characterised spectroscopically and found not to react with H-2 at room temperature. Preliminary in situ NMR measurements have shown that under the conditions of the catalysis either phosphine or pyridine can be replaced by a CO ligand. This results in a marked decrease in the activity of the rhodium centre towards oxidative addition of hydrogen and in the stability, with respect to elimination of H-2, of the dihydride.

  DOI：

  10.1039/dt9940002875