| 191232-78-7

• CAS: 191232-78-7
• 化学式: C₂₉H₂₆Fe₂N₂O₅S₂
• 分子量: 658.362
• InChiKey: QJHQLXQBOLNVTF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  diiron nonacarbonyl 、 N-(5-methyl-2-thienylmethylidene)aniline 以 四氢呋喃 为溶剂， 以1%的产率得到
  参考文献：
  名称：

  Reaction of a Thienyl Schiff Base with Diiron Nonacarbonyl:  Characterization and Structures of [μ-N-(((2,3-η¹:η²)-5-Methyl-2-thienyl)methyl)-η¹:η¹(N)- anilino]hexacarbonyldiiron and [μ-N-((Anilino(2-thienyl)methyl)((2,3-η¹:η²)-2-thienyl)methyl)- η¹:η¹(N)-anilino]hexacarbonyldiiron

  摘要：

  When thienyl Schiff base 1 reacted with Fe-2(CO)(9) under very mild conditions in benzene three major products were obtained: (1) a cyclometalated (mu-eta(1):eta(2)-thienyl; eta(1) eta(1)(N))-hexacarbonyldiiron complex, 2, (2) a hexacarbonyldiiron complex with an organic ligand, which is composed of two thienyl moieties derived from the original thienyl imine and coupled together by a C-C bond, 3, and (3) a hydrogenation product of the original thienyl Schiff base. Molecular structures of compounds 2b and 3a have been determined by single-crystal X-ray diffraction.

  DOI：

  10.1021/om961092x