Mn(2,3,7,8,12,13,17,18-octachlorotetrakis(ortho-dichlorophenyl)porphyrin)Cl | 159161-81-6

• 英文名称: Mn(2,3,7,8,12,13,17,18-octachlorotetrakis(ortho-dichlorophenyl)porphyrin)Cl
• 英文别名: [MnCl(2,3,7,8,12,13,17,18-octachloro-5,10,15,20-tetrakis-(2',6'-dichlorophenyl)porphirine)]；[MnCl(TDCP(βCl8)P)]；Mn[(Cl8)TDCPP]Cl；Mn[2,3,7,8,12,13,17,18-octachloro-5,10,15,20-tetrakis(2',6'-dichlorophenyl)porphyrin-2H]Cl；chloromanganese(III) meso-tetrakis(C6H3Cl2) octa(β-chloro) porphyrin
• CAS: 159161-81-6
• 化学式: C₄₄H₁₂Cl₁₇MnN₄
• 分子量: 1254.25
• InChiKey: IINJZRPWHZMCFP-KXMZQQCASA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氯 、 chloro(meso-tetrakis(2,6-dichlorophenyl)porphyrinato)manganese(III) 在 三氯化铝 作用下， 以 further solvent(s) 为溶剂， 生成 Mn(2,3,7,8,12,13,17,18-octachlorotetrakis(ortho-dichlorophenyl)porphyrin)Cl
  参考文献：
  名称：

  Banfi, Stefano; Mandelli, Roberta; Montanari, Fernando, Gazzetta Chimica Italiana, 1993, vol. 123, p. 409 - 416

  摘要：

  DOI：
• 作为试剂：
  描述：

  顺-环辛烯 在 sodium benzoate 、 Mn(2,3,7,8,12,13,17,18-octachlorotetrakis(ortho-dichlorophenyl)porphyrin)Cl 、 双氧水 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 生成 氧化环辛烯
  参考文献：
  名称：

  Banfi, Stefano; Mandelli, Roberta; Montanari, Fernando, Gazzetta Chimica Italiana, 1993, vol. 123, # 7, p. 409 - 415

  摘要：

  DOI：

文献信息

• Manganese(III) porphyrins as catalysts for the oxidation of aromatic substrates: An insight into the reaction mechanism and the role of the cocatalyst
  作者：Pietro Tagliatesta、Davide Giovannetti、Alessandro Leoni、Maria G.P.M.S. Neves、José A.S. Cavaleiro

  DOI：10.1016/j.molcata.2006.02.043

  日期：2006.6

  Manganese porphyrins bearing electron-withdrawing nitro substituents on the beta-positions catalyse the oxidation of activated aromatic compounds by hydrogen peroxide. The reaction yields based on the starting compounds, are largely lowered by complexation of the metal by the final or starting phenolic compounds and depend on the concentration of the added co-catalyst, e.g. imidazole.Using hindered silyl or sec-butyl ether derivatives of cresol, the reaction gives better results. In this case, it is possible to isolate the corresponding benzyl alcohol and benzoic acid derivatives in a moderate yield for such substrates. For the sec-butyl ether derivative, the corresponding quinone has also been isolated. The conversion of the benzyl alcohols into the benzoic acid derivatives under the experimental conditions was also demonstrated. (c) 2006 Elsevier B.V. All rights reserved.