Ru(2,6-(CH2P-tBu2)2C6H3)(CO)(NHPh) | 726138-53-0

• 英文名称: Ru(2,6-(CH2P-tBu2)2C6H3)(CO)(NHPh)
• CAS: 726138-53-0
• 化学式: C₃₁H₄₉NOP₂Ru
• 分子量: 614.754
• InChiKey: FEZNAJQRKUDAGM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  lithium anilide 、 [(2,6-(CH2P(C(CH3)3)2)2C6H3)Ru(CO)(OSO2CF3)] 以 四氢呋喃 为溶剂， 以50%的产率得到Ru(2,6-(CH2P-tBu2)2C6H3)(CO)(NHPh)
  参考文献：
  名称：

  Ruthenium(II) Anilido Complex Containing a Bisphosphine Pincer Ligand:  Reversible Formation of Amidinate Ligands via Intramolecular C−N Bond Formation

  摘要：

  The reaction of the octahedral anilido complex (PCP)Ru(CO)(NHPh)(PMe3) with acetonitrile produces the amidinate complex (PCP)Ru(CO){N(H)C(Me)N(Ph)}. Mechanistic studies indicate that the reaction proceeds through coordination of the nitrile to the Ru(II) metal center, followed by intramolecular nucleophilic addition of the amido ligand.

  DOI：

  10.1021/om0497543