[PtBr2(BzAsMe2)2] | 562050-00-4

• 英文名称: [PtBr2(BzAsMe2)2]
• CAS: 562050-00-4
• 化学式: C₁₈H₂₆As₂Br₂Pt
• 分子量: 747.136
• InChiKey: CXIFIPZAWOPZNC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  benzyl-dimethyl-arsine 以 丙酮 、 苯 为溶剂， 生成 [PtBr2(BzAsMe2)2]
  参考文献：
  名称：

  Configurational selectivity in benzyldimethylarsine complexes of palladium(II) and platinum(II): synthesis, spectroscopy and structures

  摘要：

  Benzyldimethylarsine complexes of palladium(II) and platinum(II) with the formulae [MX2(BzAsMe(2))(2)] (X = Cl, Br, I), [M2Cl2(mu-Cl)(2)(BzAsMe(2))(2)], [Pd2Cl2(mu-OAc)(2)(BzAsMe(2))(2)], [Pd2Me2(mu-Cl)(2)(BzAsMe(2))(2)] and [Pd2X2(mu-N <^> N)(2)(BzAsMe(2))(2)] (M = Pd or Pt; N <^> N = pyrazolate (pz) or 3,5-dimethylpyrazolate (dmpz)) have been prepared. All complexes have been characterised by elemental analysis, IR, UV-Vis absorption and NMR (H-1, C-13, Pt-195) spectroscopy. The molecular structures of the complexes [MX2(BzAsMe(2))(2)] (M = Pt or Pd; X = Cl, Br or I) have been established by NMR spectroscopy and single crystal X-ray diffraction analysis and reveal a clear dichotomy in solution and in the solid between the compounds with X = Cl in a cis configuration and the trans configured bromide and iodide complexes. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01375-0