Re4(μ3-S)4(TeCl2)4Cl8 | 186195-56-2

• 英文名称: Re4(μ3-S)4(TeCl2)4Cl8
• CAS: 186195-56-2
• 化学式: Cl₁₆Re₄S₄Te₄
• 分子量: 1950.74
• InChiKey: KCJWHAMMHPHKRA-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Re4(μ3-S)4(TeCl2)4Cl8 、 N,N-二甲基甲酰胺 以 not given 为溶剂， 生成 Re4(μ3-S)4(DMF)4Cl8
  参考文献：
  名称：

  Mironov, Yuri V.; Albrecht-Schmitt, Thomas E.; Ibers, James A., Inorganic Chemistry, 1997, vol. 36, p. 944 - 946

  摘要：

  DOI：
• 作为产物：
  描述：

  碲化氢 、 rhenium(V) chloride 、 sulfur 以 not given 为溶剂， 生成 Re4(μ3-S)4(TeCl2)4Cl8
  参考文献：
  名称：

  Two types of coordination polymers based on cluster anions [Re4Q4(CN)12]4− (Q=S, Se) and cations of rare-earth metals Ln3+: Syntheses and crystal structures

  摘要：

  The reactions of aqueous solutions of the tetrahedral cluster anions [Re(4)Q(4)(CN)(12)](4-) (Q= S. Sc) with lanthanide chlorides resulted in the crystallization of the formed compounds into two main structural types Ln(H2O)(4)(H2O)(2/3)Cl-1/3)(3)(Re(4)Q(4)(CN)(12)}2]center dot 2H(2)O (Ln= La-Cd. Q= S. Se) and K-0.5(H)(0.5)[{Ln(H2O)(4)} (Re4S4(CN)(12)}]center dot nH(2)O or (H)[{Ln(H2O)(4)}{Re4Se4(CN)(12)}]center dot 2H(2)O (Ln = Tb-Lu). Compounds of the first type crystallize in the hexagonal crystal system (space group P6(3)/m) and they have a three-dimensional polymeric structure; compounds of the second type crystallize in the orthorhombic crystal system (space group Cmcm) and they have a two-dimensional crystal structure due to the polymeric anion {[{Ln(H2O)(4)}{Re(4)Q(4)(CN)(12)}](-)}(infinity infinity). (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.02.051

文献信息

• Synthesis and structures of new compounds based on tetrahedral rhenium chalcocyanide cluster anions [Re4Q4(CN)12]4− (Q = S or Se) and [Cu(bipy)2]2+ cations
  作者：O. A. Efremova、Yu. V. Mironov、N. V. Kuratieva、V. E. Fedorov

  DOI：10.1007/s11172-006-0535-1

  日期：2006.11

  The reactions of the rhenium chalcocyanide cluster salts K4[Re4Q4(CN)12]·6H2O (Q = S or Se) with Cu2+ cations coordinated by the bidentate ligand 2,2′-bipyridyl (bipy) produced two new cluster compounds, [Cu(NH3)(bipy)2]2[Re4S4(CN)12]·bipy·3.25H2O (1) and [Cu(bipy)2}2Re4Se4(CN)12]·bipy·8.5H2O (2). The structures of these complexes were solved by X-ray diffraction. Compound 1 is ionic. Compound 2 is

  铼硫氰化物簇盐 K4[Re4Q4(CN)12]·6H2O（Q = S 或 Se）与由双齿配体 2,2'-联吡啶（bipy）配位的 Cu2+ 阳离子的反应产生了两种新的簇化合物，[Cu (NH3)(bipy)2]2[Re4S4(CN)12]·bipy·3.25H2O (1) 和 [Cu(bipy)2}2Re4Se4(CN)12]·bipy·8.5H2O (2)。这些配合物的结构通过 X 射线衍射解析。化合物 1 是离子型的。化合物 2 是分子式的。在这两种化合物的结构中，Cu(bipy)2}2+ 阳离子部分和溶剂化物 2,2'-联吡啶分子之间存在铆接相互作用。
• First Examples of Chalcofluoride Rhenium Cluster Complexes with Cubane‐Like Anions [Re ₄ Q ₄ F ₁₂ ] ^4– (Q = S, Se)
  作者：Yuri V. Mironov、Spartak S. Yarovoi、Dmitry Y. Naumov、Natalia V. Kuratieva、Svetlana G. Kozlova、Arndt Simon、Vladimir E. Fedorov

  DOI：10.1002/ejic.200500130

  日期：2005.6

  group P with four formula units per cell [a = 10.6451(3) A, b = 14.6853(4) A, c = 16.9349(5) A, α = 66.8420(10)°, β = 84.8460(10)°, γ = 85.5740(10)°, V = 2421.69(12) A3 (T = 293 K)]. Hydrophilic terminal fluoride ligands of cluster anions are included in the hydrogen bond systems of their hydrate shells. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

  通过 Re4Q4(TeCl2)4Cl8 (Q = S, Se) 与熔融的 KHF2。两种化合物均已通过单晶 X 射线衍射方法进行了表征。化合物 1 在三角空间群 R 中结晶，每个单元有 24 个分子式单位 [a = b = 23.6503(3) A, c = 25.2697(7) A, V = 12240.6(4) A3 (T = 293 K)]；化合物 2 在单斜空间群 P 中结晶，每个单元有四个分子式单元 [a = 10.6451(3) A, b = 14.6853(4) A, c = 16.9349(5) A, α = 66.8420(10)°, β = 84.8460(10)°, γ = 85.5740(10)°, V = 2421.69(12) A3 (T = 293 K)]。簇阴离子的亲水末端氟化物配体包含在其水合物壳的氢键系统中。(© Wiley-VCH Verlag GmbH
• Tetrahedral chalcogeno thiocyanate cluster complexes [Re4Q4(SCN)12]4− (Q=S, Se, Te): synthesis and crystal structures
  作者：Yuri V. Mironov

  DOI：10.1016/s0277-5387(99)00382-4

  日期：2000.2

  The [Re(4)Q(4)(SCN)(12)](4-) (Q = S, Se, Te) anions were obtained by the reactions of neutral molecular clusters Re44QCl8(TeCl2)(4), Q = S, Se, Te, with melting KSCN. Crystal structures were determined for the isostructural compounds (Ph4P)(4)Re-44S(SCN)(12) (1), (Ph4P)(4)Re4Se4(SCN)(12) (2) and (Ph4As)(4)Re(4)T4(e)(SCN)(12) (3). Each contains an Re(4)Q(4) cubane-like cluster core with Re-Re distances in the ranges 2.762(3)-2.768(2) Angstrom (1), 2.799(2)-2.803(2) Angstrom (2) and 2.864(2)-2.877(2) Angstrom (3). The faces of the Re, units are symmetrically capped by triply bridging chalcogenide ligands Q(2-) (Q = S, Se, Te). (C) 2000 Elsevier Science Ltd All rights reserved.