Hydride addition to [η5-indenyl) Fe (CO)3] BF4: evidence for η 3-indenyl intermediates
摘要:
Spectroscopic evidence is presented for the formation at low temperatures of the eta-3-indenyl intermediate [(eta-3-C9H7)Fe(CO)3H], prior to formation of the normal hydride, [(eta-5-C9H7)Fe(CO)2H], by reduction of the tricarbonylironindenyl cation with sodium cyanoborohydride in acetone.