(C5H5)Fe(C5H3)(P(C6H4CF3-p)2)(CHNCH(C6H4CH3-p)Ph) | 394729-62-5

• 英文名称: (C5H5)Fe(C5H3)(P(C6H4CF3-p)2)(CHNCH(C6H4CH3-p)Ph)
• CAS: 394729-62-5
• 化学式: C₃₉H₃₀F₆FeNP
• 分子量: 713.485
• InChiKey: MSLFKMUZEJJYJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  α-(C6H4CF3-p)ferrocenecarboxaldehyde 、 [(4-甲基苯基)(苯基)甲基]胺盐酸盐 在 molecular sieve 作用下， 以 二氯甲烷 为溶剂， 以80%的产率得到(C5H5)Fe(C5H3)(P(C6H4CF3-p)2)(CHNCH(C6H4CH3-p)Ph)
  参考文献：
  名称：

  Preparation and application of polymer-supported π-allylpalladium complex as a chiral catalyst in the asymmetric allylic alkylation

  摘要：

  Chiral ferrocenylphosphine-imines A-D were synthesized and grafted to polystyrene to afford polymeric ligands PA-PD. Ligands A-D and PA-PD were used as ligands in the palladium-catalyzed asymmetric allylic alkylation. In the homogeneous reactions, the best result was obtained when the ligand A was used (99% yield and 82% ce). In the heterogeneous reactions, the highest ce value (73%) in the first run was obtained when PA was used as a ligand. Considering the enantioselectivity and reusability, the best result was obtained in the case of PC. The recycling of the polymer-supported pi -allylpalladium catalyst gave unsatisfactory results: it can be reused three times with moderate enantioselectivities (60-70% ee). (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(01)00198-4