| 200572-21-0

• CAS: 200572-21-0；200572-19-6
• 化学式: C₁₇H₁₂Fe₂O₇STe
• 分子量: 599.638
• InChiKey: YAYLWDPLKVRJPM-RJNCWIIDSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (CO)6Fe2STe(μ-C(Ph)=CC(OEt)=Cr(CO)5) 以 四氢呋喃 为溶剂， 以9%的产率得到[(CO)6Fe2(μ-SCPh=CTeCH(OEt))]2
  参考文献：
  名称：

  Isolation and characterization of [Fe2(CO)6Se2{μ-(CO)3Cr(η5-C5(H)(CH2Ph)(Ph)(OEt)}], [(CO)6Fe2{μ-EC(Ph)C(E′)C(H)(OEt)}]2 and [(CO)6Fe2{μ-SC(H)(Ph)C(Te)C(H)(OEt)}] from the thermolysis of Fischer carbene adducts [(CO)6Fe2EE′{μ-C(Ph)C–C(OEt)Cr(CO)5}] (E, E′=Se and E=S, E′=Te)

  摘要：

  Thermolysis of the trimetallic adducts [(CO)(6)Fe2EE'{mu-C(Ph)=C-C(OEt)=Cr(CO)(5)}] 1a,b (1a: E = E' = Se; 1b: E = S, E' = Te) in refluxing THF yield the following complexes: [Fe-2(CO)(6)EE' {mu-(CO)(3)Cr(eta(5)-C-5(H)(CH2Ph)(Ph)(OEt)}], (2: E = E' = Se); [(CO)(6)Fe-2{mu-EC(Ph)=C(E')C(H)(OEt)}](2), (3a: E = E' = Se; 3b: E = S, E' = Te) and [(CO)(6)Fe-2{mu-EC(H)(Ph)C(E')=C(H)(OEt)}], (4: E = S, E' = Te), where the product formation depends on the nature of chalcogen atoms present in the trimetallic adducts 1a and 1b. All products have been characterized by IR and H-1-,C-13-, Se-77- and Te-125-NMR spectroscopy and structural types were unequivocally established by X-ray crystallographic analysis of compounds 3a and 4. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00646-9