[Ti(μ-η5-C5Me4SiMe2O-κO)(μ-O)]6*CH3(CH2)3CH3 | 1025513-99-8

• 英文名称: [Ti(μ-η5-C5Me4SiMe2O-κO)(μ-O)]6*CH3(CH2)3CH3
• CAS: 1025513-99-8
• 化学式: C₅H₁₂*C₆₆H₁₀₈O₁₂Si₆Ti₆
• 分子量: 1621.52
• InChiKey: KNJXJULUTFOBKP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(Ti(μ-(η5-C5Me4SiMe2O-κO)))Cl]2(μ-O) 、 lithium hydroxide 、 正戊烷 在 N(CH₂CH₃)3 作用下， 以 not given 为溶剂， 生成 [((TiCl)(Ti)[μ-(η5-C5Me4SiMe2O-κO)]2(μ-O))2(μ-O)] 、 [Ti(μ-η5-C5Me4SiMe2O-κO)(μ-O)]6*CH3(CH2)3CH3
  参考文献：
  名称：

  Organotitanoxanes with Unique Structure among Transition-Element Organometallic Oxide Derivatives

  摘要：

  The synthesis of novel titanoxane compounds, [{(TiCl)(Ti)[mu-(eta(CMe4SiMe2O)-C-5-Me-5-kappa O)](2)(mu-O)}(2)(mu-O)] (4) and [{Ti[mu-(eta(5)-(CMe4SiMe2O)-Me-5-kappa O)](mu-O)}(6)] (5), by controlled hydrolysis of a dinuclear titanium/oxo complex is described. Complexes 4 and 5 show unprecedented structural features for organometallic oxide derivatives of transition elements and represent unique fully characterized examples of tetra- and hexanuclear organo-transition-metal oxide compounds with an open-chain and a monocyclic structure, respectively.

  DOI：

  10.1021/ic8003646