N-(para-(ferrocenyl)benzoyl)-glycine-glycine ethyl ester | 942590-93-4

• 英文名称: N-(para-(ferrocenyl)benzoyl)-glycine-glycine ethyl ester
• CAS: 942590-93-4
• 化学式: C₂₃H₂₄FeN₂O₄
• 分子量: 448.302
• InChiKey: CFCKGJOVCVOSGR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  para-(ferrocenyl)benzoic acid 、 H-gly-gly-oet.盐酸盐 在 1-羟基苯并三唑 、 三乙胺 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 以56%的产率得到N-(para-(ferrocenyl)benzoyl)-glycine-glycine ethyl ester
  参考文献：
  名称：

  Synthesis and characterization of novel N-para-ferrocenyl benzoyl dipeptide esters

  摘要：

  N-para-ferrocenyl benzoyl dipeptide esters 2-5 were prepared by coupling para-ferrocenyl benzoic acid I to the dipeptide ethyl esters GlyGly(OEt) 2, GlyAla(OEt) 3, GlyLeu(OEt) 4 and GlyPhe(OEt) 5. The compounds were fully characterized by a range of NMR spectroscopic techniques.. mass spectrometry (ESI-MS, FABMS, MS/MS) and cyclic voltammetry (CV). The a(1) and b(1) ions appeared at one mass unit less than the expected mass in the tandem mass spectra. The CV curves of compounds 2-5 exhibited quasi-reversible redox behavior similar to the Fc/Fc(+) redox couple and displayed oxidation potential values in the 50-55 mV range, against the Fc/Fc+ redox couple. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.06.013