sodium (R,S)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-diamino-propionate manganese(III) chloride | 951009-47-5

• 英文名称: sodium (R,S)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-diamino-propionate manganese(III) chloride
• 英文别名: ClMn((NaOOC)(C2H3)(NCH(C6H2)(O)(tBu)2)2)；[Mn(III)Cl(Na(bsalcen))]
• CAS: 951009-47-5
• 化学式: C₃₃H₄₅ClMnN₂O₄*Na
• 分子量: 647.112
• InChiKey: PAULDNYJJOASBD-DFNZVVRSSA-J

反应信息

• 作为产物：
  描述：

  氯化镁四氢呋喃聚合物 、 Na((R)-H2bsalcen) 在 N(C₂H₅)3 、 air 作用下， 以 四氢呋喃 为溶剂， 以90%的产率得到sodium (R,S)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-diamino-propionate manganese(III) chloride
  参考文献：
  名称：

  衍生自O-官能化二胺的可溶单金属salen络合物，作为金属配体，用于合成异双金属络合物†

  摘要：

  O功能化Salen 配体在合成均金属和杂金属时用作桥联配体 Salen与早期和晚期过渡金属的络合物（H 2 salen：N，N'-双（水杨基）乙二胺，系统名称： 2,2'-{乙烷-1,2-二基双（亚硝甲基亚甲基）}二酚）。一种新型的O功能化Salen 合成了含烷基的配体，以增强其在有机溶剂中的溶解度以及 羧基组允许引入早期过渡金属。两个新Salen衍生自O-官能化二胺的配体由3,5-二叔丁基水杨醛 （基底） 和 3,4-二氨基苯甲酸 （4cpn）或 （R）-2,3-二氨基丙酸 （岑）。通过使用芳基二胺，可获得共轭骨架，并且烷基二胺可用于引入手性中心。这Salen 来自的配体 3,4-二氨基苯甲酸只能通过锌（II）介导的模板反应访问。单金属的Salen 可以通过模板合成获得配合物 镍（II） 和 铜（II）。类似的铬（III）， 锰（III） 和 钼（IV）salen配合物是直接从salen

  DOI：

  10.1039/b920706f

文献信息

• Epoxidation of olefins catalyzed by novel Mn(III) and Mo(IV) Salen complexes immobilized on mesoporous silica gelPart I. Synthesis and characterization of homogeneous and immobilized Mn(III) and Mo(IV) Salen complexes
  作者：Tatiana Luts、Wladimir Suprun、Diana Hofmann、Olaf Klepel、Helmut Papp

  DOI：10.1016/j.molcata.2006.07.035

  日期：2007.1.2

  New ways of the covalent immobilization of Mn(III) and Mo(IV) Salen complexes on a mesoporous silica support to produce a stable heterogeneous catalyst for epoxidation reactions are reported. Peptide and ester interactions were employed to anchor the metal Salen complex on the organo-modified silica framework. Electrospray MS, FTIR, TGA, ICP-OES and elemental analysis were used for quantitative and qualitative analyses of the immobilized Salen complexes. The results confirm the location of the metal Salen complex inside the mesopores covalently attached to the silica framework. (c) 2006 Elsevier B.V. All rights reserved.
• Novel ways of Mn-Salen complex immobilization on modified silica support and their catalytic activity in cyclooctene epoxidation
  作者：T. Luts、H. Papp

  DOI：10.1134/s0023158407010235

  日期：2007.2

  The covalent immobilization of Mn(III)-Salen complexes on an amorphous mesoporous silica support is reported. Both (3-aminopropyl)trimethoxysilane (APTMS) and (3-iodopropyl)trimethoxysilane (IPTMS) were used in a post-synthesis grafting method to prepare organosilane-modified porous materials. Peptide and ester interactions were employed to anchor the Salen complex to the silica framework. The catalytic activity of the immobilized Salen catalyst was studied by epoxidation of cyclooctene. The comparison of the homogeneous and the immobilized catalyst shows that there was no significant loss of catalytic activity for epoxidation by immobilization. In the current study, the effects of reaction temperatures, solvents, and amount of catalyst on the catalytic activity were investigated. The optimal yield of cyclooctene oxide was obtained at 45 degrees C using toluene as the solvent.