(hydrotris(3-tert-butyl-5-methyl-1-pyrazolyl)borate)nitratocopper(II) | 359417-83-7

• 英文名称: (hydrotris(3-tert-butyl-5-methyl-1-pyrazolyl)borate)nitratocopper(II)
• CAS: 359417-83-7
• 化学式: C₂₄H₄₀BCuN₇O₃
• 分子量: 548.984
• InChiKey: DFAMBCFWCRUEQC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  copper(II) nitrate trihydrate 、 potassium hydrotris(3-tert-butyl-5-methyl-1-pyrazolyl)borate 以 二氯甲烷 、 丙酮 为溶剂， 以76%的产率得到(hydrotris(3-tert-butyl-5-methyl-1-pyrazolyl)borate)nitratocopper(II)
  参考文献：
  名称：

  三(吡唑基)硼酸盐对硝基铜(II)配合物的结构影响

  摘要：

  描述了对由一系列氢化三（吡唑基）硼酸盐连接的硝基铜 (II) 配合物的一些结构影响。吡唑环的 5 位和 3 位对于提供配位结构很重要。

  DOI：

  10.1246/bcsj.74.1065

文献信息

• Copper(II) nitrato and chloro complexes with sterically hindered tridentate ligands: Influence of ligand framework and charge on their structure and physicochemical properties
  作者：Kiyoshi Fujisawa、Hiroaki Iwamoto、Kengo Tobita、Yoshitaro Miyashita、Ken-ichi Okamoto

  DOI：10.1016/j.ica.2009.05.016

  日期：2009.9

  Copper(II) coordination complexes of the neutral ligand, tris(3-tert-butyl-5-methyl-1-pyrazolyl) methane (L2'), i.e. the copper(II) nitrato complexes [Cu(L2')(NO3)][Cu(NO3)4](1/2) (1) and [Cu(L2')(NO3)](ClO4) (2) and the copper(II) chloro complex [Cu(L2')(Cl)](ClO4) (3), and its anionic borate analogue, hydrotris(3-tert- butyl-5-methyl-1-pyrazolyl) borate (L2), i. e. the copper(II) nitrato complex [Cu(L2)(NO3)] (4) and the copper(II) chloro complex [Cu(L2)(Cl)] (5), were synthesized in order to investigate the influence of ligand framework and charge on their structure and physicochemical properties. While X-ray crystallography did not show any definitive trends in terms of copper(II) atom geometry in four-coordinate copper(II) chloro complexes 3 and 5, different structural trends were observed in five-coordinate copper(II) nitrato complexes 1, 2, and 4. These complexes were also characterized by spectroscopic techniques, namely, UV-Vis, ESR, IR/far-IR, and X-ray absorption spectroscopy. (C) 2009 Elsevier B. V. All rights reserved.