Cp2Zr(CH(CH3)C(CH3)CHN(tBu)) | 1027098-28-7

• 英文名称: Cp2Zr(CH(CH3)C(CH3)CHN(tBu))
• CAS: 1027098-28-7
• 化学式: C₁₉H₂₇NZr
• 分子量: 360.654
• InChiKey: DZOMJSDPIMBAQS-IRYVOTIRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Cp2Zr(CH(CH3)C(CH3)CHN(tBu)) 、 二氯苯酚溴酯 以 not given 为溶剂， 生成 PhB(CH(CH3)C(CH3)CHN(tBu))
  参考文献：
  名称：

  Anionic Multisubstituted 1,2-Azaborolyl Ligands: Syntheses, Characterization, and Coordination Chemistry

  摘要：

  Two synthetic methods for the preparation of tri- or tetrasubstituted 1,2-azaborolyls (Ab) are described. Both tri- and tetrasubstituted Ab rings can be conveniently attained via either dilithiation-directed or Cp(2)Zr(II)-mediated cyclization followed by transmetalation in good yields. In particular, anionic 1,2,4-trimethyl-1,2-azaborolyl and 1,2,3,4-tetramethyl-1,2-azaborolyl, readily prepared through our methods, have been demonstrated as good supporting ancillary ligands in group IV metal complexes.

  DOI：

  10.1021/om8001075
• 作为产物：
  描述：

  二氯二茂锆 、 MeCH=CMeCH=N(CMe3) 在 CH₃CH₂CH₂CH₂Li 作用下， 以 not given 为溶剂， 生成 Cp2Zr(CH(CH3)C(CH3)CHN(tBu))
  参考文献：
  名称：

  Anionic Multisubstituted 1,2-Azaborolyl Ligands: Syntheses, Characterization, and Coordination Chemistry

  摘要：

  Two synthetic methods for the preparation of tri- or tetrasubstituted 1,2-azaborolyls (Ab) are described. Both tri- and tetrasubstituted Ab rings can be conveniently attained via either dilithiation-directed or Cp(2)Zr(II)-mediated cyclization followed by transmetalation in good yields. In particular, anionic 1,2,4-trimethyl-1,2-azaborolyl and 1,2,3,4-tetramethyl-1,2-azaborolyl, readily prepared through our methods, have been demonstrated as good supporting ancillary ligands in group IV metal complexes.

  DOI：

  10.1021/om8001075