{(η6-1,3.5-C6H3)ClRu(SMe2)2}PF6 | 136345-95-4

• 英文名称: {(η6-1,3.5-C6H3)ClRu(SMe2)2}PF6
• CAS: 136345-95-4
• 化学式: C₁₃H₂₄ClRuS₂*F₆P
• 分子量: 525.953
• InChiKey: QZRRFUKSIMSPMJ-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  {(η6-1,3.5-C6H3)ClRu(SMe2)2}PF6 、 苯乙炔 以 甲醇 为溶剂， 以50%的产率得到{(η6-1,3,5-Me3C6H3)ClRu(SMe2)(C(OMe)CH2Ph)}PF6
  参考文献：
  名称：

  (Dialkylsulfide)(arene)ruthenium(II) derivatives

  摘要：

  The preparations are reported of neutral and cationic (dialkylsufide)(eta-6-arene)ruthenium(II) complexes of the types (eta-6-arene)Cl2Ru(SR2), [(eta-6-arene)ClRu(SR2)2]+ and [(eta-6-arene)ClRu(SR2)(L)]+. These complexes containing labile R2S-Ru bonds can be used in the ready generation of 16 electron ruthenium moieties for the activation of terminal alkynes and access to cationic (carbene)(eta-6-arene)ruthenium(II) derivatives such as {(1,3,5-Me3C6H3)ClRu(SMe2)[C(OMe)CH2Ph]}+ and {(C6Me6)ClRu(PMe3)[C(OMe)CH2Ph]}+.

  DOI：

  10.1016/0022-328x(91)86026-m
• 作为产物：
  描述：

  sodium hexaflorophosphate 、 dichloro(mesitylene)ruthenium(II) dimer 、 二甲基硫 以 丙酮 为溶剂， 以70%的产率得到{(η6-1,3.5-C6H3)ClRu(SMe2)2}PF6
  参考文献：
  名称：

  (Dialkylsulfide)(arene)ruthenium(II) derivatives

  摘要：

  The preparations are reported of neutral and cationic (dialkylsufide)(eta-6-arene)ruthenium(II) complexes of the types (eta-6-arene)Cl2Ru(SR2), [(eta-6-arene)ClRu(SR2)2]+ and [(eta-6-arene)ClRu(SR2)(L)]+. These complexes containing labile R2S-Ru bonds can be used in the ready generation of 16 electron ruthenium moieties for the activation of terminal alkynes and access to cationic (carbene)(eta-6-arene)ruthenium(II) derivatives such as {(1,3,5-Me3C6H3)ClRu(SMe2)[C(OMe)CH2Ph]}+ and {(C6Me6)ClRu(PMe3)[C(OMe)CH2Ph]}+.

  DOI：

  10.1016/0022-328x(91)86026-m