(((diphenylphosphoryl)amino)diphenyl-l5-phosphaneyl)gold(II) chloride | 176968-30-2

• 英文名称: (((diphenylphosphoryl)amino)diphenyl-l5-phosphaneyl)gold(II) chloride
• CAS: 176968-30-2
• 化学式: C₂₄H₂₁AuClNOP₂
• 分子量: 633.804
• InChiKey: APFRCVDCVJOQMQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (((diphenylphosphoryl)amino)diphenyl-l5-phosphaneyl)gold(II) chloride 、 tetraphenylimidothioxodiphosphinic acid potassium salt 以 甲醇 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Slawin, Alexandra M. Z.; Smith, Martin B.; Woollins, J. Derek, Journal of the Chemical Society, Dalton Transactions, 1998, # 10, p. 1537 - 1539

  摘要：

  DOI：
• 作为产物：
  描述：

  (tetrahydrothiophene)gold(I) chloride 、 (diphenylphosphinoamino)diphenylphosphine oxide 以 二氯甲烷 为溶剂， 以88%的产率得到(((diphenylphosphoryl)amino)diphenyl-l5-phosphaneyl)gold(II) chloride
  参考文献：
  名称：

  具有杂官能膦Ph 2 PNHP（O）Ph 2的后期过渡金属配合物

  摘要：

  的配合物[的MC1（COD）（HL）]（M =铑或铱），[的PdCl（η 3 -C 3 H ^ 5）（HL）]，[的PdCl（L-L）（HL）]，反式- [ RhCl（CO）（HL）2 ]和[AuCl（HL）]是通过[{M（µ-Cl）（cod）} 2 ]（M = Rh或Ir; cod =环辛1-1， 5二烯），[{的Pd（μ-Cl）的（η 3 -C 3 H ^ 5）} 2 ]，[{的Pd（μ-Cl）的（L-L）} 2 ]（L-L = C 12 ħ 12 N，C 10 H 8 N或C 9 H 12 N），[{Rh（µ-Cl）（CO）2 } 2]或[AuCl（tht）]（tht =四氢噻吩）与Ph 2 PNHP（O）Ph 2（HL）。在所有这些络合物中，配体都是单价的P结合的。从氯化物抽象[的PdCl（C 12 H ^ 12 N）（HL）]或[的PdCl（η 3 -C 3 H ^ 5）（HL）]时，使用的Ag

  DOI：

  10.1039/dt9960001283

文献信息

• New hydrogen-bonded dimeric and polymeric gold(I) complexes of the heterodifunctional ligand Ph2PNHP(O)Ph2
  作者：Alexandra M.Z Slawin、Martin B Smith、J.Derek Woollins

  DOI：10.1016/s0277-5387(98)00405-7

  日期：1999.3

  The preparation of several new gold(I) complexes by chloride metathesis of [AuCl(HL)] [HL=Ph2PNHP(O)Ph-2] with either HL or K[Ph2P(E)NP(E)Ph-2] (E=S or Se) is described. All compounds were characterised by a combination of P-31H-1}, H-1 and IR spectroscopy, microanalysis and X-ray crystallography. X-ray structural studies reveal that [Au(HL)(2)]Cl [monoclinic, space group P2(1)/c, a=9.0726(3) Angstrom, b=21.0847(6) Angstrom, c=12.0131(3) Angstrom, beta=105.1090(10)degrees, V=2219 Angstrom(3), Z=2, final R=3.97] forms a one dimensional polymeric structure in which alternating [Au(HL)(2)](+) and Cl- ions are linked through intermolecular N-K ... Cl hydrogen-bonding. In contrast the three-co-ordinate compound [AuPh2P(Se)NP(Se)Ph-2-Se,Se'}(HL)] [monoclinic, space group P2(1)/a, a=21.6752(5) Angstrom, b=9.1200(10) Angstrom, c=24.0742(7) Angstrom, beta=106.080(2)degrees, V=4573 Angstrom(3), Z=4, final R=8.94] forms hydrogen-bonded dimer pairs analogous to that previously observed in non-complexed HL. The X-ray crystal structure of the gold(I) precursor [AuCl(HL)] has also been determined: monoclinic, space group P2(1)/c, a=10.217(8) Angstrom, b =23.256(5) Angstrom, c=20.086(5) Angstrom, beta = 101.15(4)degrees, V=4683 Angstrom(3), Z=8, final R=5.2. The X-ray crystal structure reveals intermolecular N-H ... O=P hydrogen-bonding between adjacent [AuCl(HL)] molecules forming infinite chains. (C) 1999 Elsevier Science Ltd. All rights reserved.